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Pyrolysis of Huadian oil shale under catalysis of shale ash
Shi, Wanjun1; Wang, Ze1,2; Song, Wenli1,2; Li, Songgeng1,2; Li, Xiaoyang1
2017
发表期刊JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
ISSN0165-2370
卷号123页码:160-164
摘要The influence of shale ash on the pyrolysis of Huadian oil shale was investigated. It was found that under the catalysis of shale ash, aliphatics in shale oil were partially converted to aromatics, and the long-chain aliphatics were converted to shorter ones. This effect could be improved by increased content of shale ash or by augmented temperature. Beyond the Diels-Alder reaction for the formation of aromatics, a novel reaction route of cyclization of aliphatics followed by dehydrogenation to aromatics was proposed. The component of CaO in shale ash plays an important role to the general performance of shale ash. (C) 2016 Elsevier B.V. All rights reserved.
关键词Shale Ash Oil Shale Pyrolysis Catalysis
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jaap.2016.12.011
收录类别SCI
语种英语
关键词[WOS]HEATED FIXED-BED ; AROMATIC-HYDROCARBONS ; MINERAL MATRIX ; YIELD ; INTERNALS ; TEMPERATURE ; MIXTURES ; PRESSURE ; KEROGEN ; CARRIER
WOS研究方向Chemistry ; Spectroscopy
WOS类目Chemistry, Analytical ; Spectroscopy
项目资助者National Program on Key Basic Research Project (973 Program)(2014CB744304) ; National Natural Science Foundation of China(51476180)
WOS记录号WOS:000394064200019
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21991
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Ctr Mesosci, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100190, Peoples R China
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Shi, Wanjun,Wang, Ze,Song, Wenli,et al. Pyrolysis of Huadian oil shale under catalysis of shale ash[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,2017,123:160-164.
APA Shi, Wanjun,Wang, Ze,Song, Wenli,Li, Songgeng,&Li, Xiaoyang.(2017).Pyrolysis of Huadian oil shale under catalysis of shale ash.JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,123,160-164.
MLA Shi, Wanjun,et al."Pyrolysis of Huadian oil shale under catalysis of shale ash".JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS 123(2017):160-164.
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