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Graphene Oxide-Polymer Composite Langmuir Films Constructed by Interfacial Thiol-Ene Photopolymerization
Luo, Xiaona1,2; Ma, Kai2; Jiao, Tifeng1,2,3; Xing, Ruirui2,3; Zhang, Lexin2; Zhou, Jingxin2; Li, Bingbing4

The effective synthesis and self-assembly of graphene oxide (GO) nanocomposites are of key importance for a broad range of nanomaterial applications. In this work, a one-step chemical strategy is presented to synthesize stable GO-polymer Langmuir composite films by interfacial thiol-ene photopolymerization at room temperature, without use of any crosslinking agents and stabilizing agents. It is discovered that photopolymerization reaction between thiol groups modified GO sheets and ene in polymer molecules is critically responsible for the formation of the composite Langmuir films. The film formed by Langmuir assembly of such GO-polymer composite films shows potential to improve the mechanical and chemical properties and promotes the design of various GO-based nanocomposites. Thus, the GO-polymer composite Langmuir films synthesized by interfacial thiol-ene photopolymerization with such a straightforward and clean manner, provide new alternatives for developing chemically modified GO-based hybrid self-assembled films and nanomaterials towards a range of soft matter and graphene applications.

KeywordGraphene Oxide Thiol-ene Photopolymerization Langmuir Film Self-assembly Composite Film
WOS HeadingsScience & Technology ; Technology ; Physical Sciences
Indexed BySCI
WOS KeywordWell-defined Polystyrene ; Graphite Oxide ; Click Chemistry ; Blodgett-films ; Raman-spectra ; Carbon ; Electrodes ; Nanosheets ; Sheets ; Functionalization
WOS Research AreaScience & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
Funding OrganizationNational Natural Science Foundation of China(21473153) ; Support Program for the Top Young Talents of Hebei Province ; China Postdoctoral Science Foundation(M580214) ; Scientific and Technological Research and Development Program of Qinhuangdao City(201502A006) ; Open Funding Project of the National Key Laboratory of Biochemical Engineering(2013KF-02)
WOS IDWOS:000397580800004
Citation statistics
Document Type期刊论文
Affiliation1.Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
2.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
3.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China
4.Cent Michigan Univ, Dept Chem & Biochem, Mt Pleasant, MI 48859 USA
Recommended Citation
GB/T 7714
Luo, Xiaona,Ma, Kai,Jiao, Tifeng,et al. Graphene Oxide-Polymer Composite Langmuir Films Constructed by Interfacial Thiol-Ene Photopolymerization[J]. NANOSCALE RESEARCH LETTERS,2017,12.
APA Luo, Xiaona.,Ma, Kai.,Jiao, Tifeng.,Xing, Ruirui.,Zhang, Lexin.,...&Li, Bingbing.(2017).Graphene Oxide-Polymer Composite Langmuir Films Constructed by Interfacial Thiol-Ene Photopolymerization.NANOSCALE RESEARCH LETTERS,12.
MLA Luo, Xiaona,et al."Graphene Oxide-Polymer Composite Langmuir Films Constructed by Interfacial Thiol-Ene Photopolymerization".NANOSCALE RESEARCH LETTERS 12(2017).
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