Solubility of FeSO4 center dot 7H(2)0 in the H2SO4-Ti(SO4)(2)-H2O, H2SO4-MgSO4-H2O, and HCI-H2O Systems from 278 to 313 K
Zhang, Yan1; Zhou, Juan2; Li, Zhibao1
2017-03-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN0021-9568
卷号62期号:3页码:973-979
摘要The solubilities of FeSO4 center dot 7H(2)O in the H2SO4Ti(SO4)(2)H2O and H2SO4MgSO4H2O systems were measured with a dynamic method from 278.15 to 308.15 K. Due to the hydrolysis property of Ti(IV), it was found that the common ion effect of Ti(SO4)(2) was not so obvious as that of MgSO4 for the solubility of FeSO4 center dot 7H(2)O. The solubility of FeSO4 center dot 7H(2)O in the HClH2O system was also measured by same method. The solubility did not change much at first, yet substantially increased when more HCl was added into the solution. New interaction parameters of ions for the mixed-solvent electrolyte (MSE) model were regressed by the experimental solubility data, with the average relative deviations of less than 5.0%. The speciation and the activity coefficients of species in the FeSO4-HCl-H2O system with an FeSO4 concentration of 1.0 mol.kg(1) were predicted by the MSE model with the newly regressed parameters at 303.15 K.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1021/acs.jced.6b00783
收录类别SCI
语种英语
关键词[WOS]SULFATE-SOLUTIONS ; NA2SIO3-CENTER-DOT-9H(2)O ; SPECIATION ; MODEL
WOS研究方向Thermodynamics ; Chemistry ; Engineering
WOS类目Thermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical
项目资助者National Natural Science Foundation of China(21506218 ; Science and Technology Planning Project of Qinghai Province(2012-G-213A) ; 21476235 ; U1407112)
WOS记录号WOS:000396295900012
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22072
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
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Zhang, Yan,Zhou, Juan,Li, Zhibao. Solubility of FeSO4 center dot 7H(2)0 in the H2SO4-Ti(SO4)(2)-H2O, H2SO4-MgSO4-H2O, and HCI-H2O Systems from 278 to 313 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2017,62(3):973-979.
APA Zhang, Yan,Zhou, Juan,&Li, Zhibao.(2017).Solubility of FeSO4 center dot 7H(2)0 in the H2SO4-Ti(SO4)(2)-H2O, H2SO4-MgSO4-H2O, and HCI-H2O Systems from 278 to 313 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,62(3),973-979.
MLA Zhang, Yan,et al."Solubility of FeSO4 center dot 7H(2)0 in the H2SO4-Ti(SO4)(2)-H2O, H2SO4-MgSO4-H2O, and HCI-H2O Systems from 278 to 313 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 62.3(2017):973-979.
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