Isobutane/butene alkylation catalyzed by ionic liquids: a more sustainable process for clean oil production
Wang, Hui1; Meng, Xiangzhan2; Zhao, Guoying1; Zhang, Suojiang1
2017-03-21
发表期刊GREEN CHEMISTRY
ISSN1463-9262
卷号19期号:6页码:1462-1489
摘要The alkylation of isobutane with butene is an important refining process for the production of a complex mixture of branched alkanes, which is an ideal blending component for gasoline. The current catalysts used in industrial processes are concentrated H2SO4 and HF, which have problems including serious environmental pollution, equipment corrosion, potential safety hazard, high energy consumption in waste acid recycling, etc. Solid catalysts are another type of catalyst for this alkylation; however, they suffer from problems related to rapid deactivation. Ionic liquids (ILs) can be considered as catalysts of the third generation to replace traditional catalysts in isobutane/butene alkylation to produce clean oil. In this review, alkylation catalyzed by various kinds of acidic ILs, including Lewis acidic ILs (such as chloroaluminate ones) and ILs containing Bronsted acidic functional groups (e.g., -SO3H ,[HSO4](-)), is reviewed. The currently reported ILs used in the catalysis of isobutane alkylation and their corresponding catalytic activity are summarized and compared. This will help the readers to know what kinds of ILs are effective for the alkylation of isobutane with butene and to understand which factors affect the catalytic performance. The advantages of the catalysis of isobutane/butene alkylation by ILs include tunable acidity of the catalyst by varying the ion structure, limited solubility of the products in the IL phase and therefore easy separation of the alkylate from the catalyst, environmental friendliness, less corrosion of equipment, etc., thus making catalysis by ILs greener. The mechanism and kinetics of the alkylation catalyzed by ILs are discussed. Finally, perspectives and challenges of the isobutane/butene alkylation catalyzed by ILs are given.
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c6gc02791a
收录类别SCI
语种英语
关键词[WOS]SOLID ACID CATALYSTS ; ISOBUTANE/2-BUTENE ALKYLATION ; C-4 OLEFINS ; ISOBUTYLENE ALKYLATION ; 2-BUTENE ALKYLATION ; REACTION MEDIA ; CHLOROALUMINATE ; TEMPERATURE ; CONVERSION ; ZEOLITES
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
项目资助者National Key Projects for Fundamental Research and Development of China(2016YFB0600903) ; Fund of State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, CAS(MPCS-2015-A-05) ; Key Program of National Natural Science Foundation of China(91434203) ; CAS Province Cooperation Program(2014JZ0012) ; National Natural Science Funds for Distinguished Young Scholars(21425625)
WOS记录号WOS:000397389900008
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22092
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wang, Hui,Meng, Xiangzhan,Zhao, Guoying,et al. Isobutane/butene alkylation catalyzed by ionic liquids: a more sustainable process for clean oil production[J]. GREEN CHEMISTRY,2017,19(6):1462-1489.
APA Wang, Hui,Meng, Xiangzhan,Zhao, Guoying,&Zhang, Suojiang.(2017).Isobutane/butene alkylation catalyzed by ionic liquids: a more sustainable process for clean oil production.GREEN CHEMISTRY,19(6),1462-1489.
MLA Wang, Hui,et al."Isobutane/butene alkylation catalyzed by ionic liquids: a more sustainable process for clean oil production".GREEN CHEMISTRY 19.6(2017):1462-1489.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wang, Hui]的文章
[Meng, Xiangzhan]的文章
[Zhao, Guoying]的文章
百度学术
百度学术中相似的文章
[Wang, Hui]的文章
[Meng, Xiangzhan]的文章
[Zhao, Guoying]的文章
必应学术
必应学术中相似的文章
[Wang, Hui]的文章
[Meng, Xiangzhan]的文章
[Zhao, Guoying]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。