CAS OpenIR  > 多相复杂系统国家重点实验室
Oxidation of Aromatic Aldehydes to Esters: A Sulfate Radical Redox System
Guo, Ya-Fei1,2; Mahmood, Sajid1,2; Xu, Bao-Hua1; Yao, Xiao-Qian1; He, Hong-Yan1; Zhang, Suo-Jiang1
2017-02-03
发表期刊JOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
卷号82期号:3页码:1591-1599
摘要A mild oxidative esterification of various aromatic aldehydes by sulfate radical redox system was presented. In the reaction pathway exploration, the transiency of MeOSO3- was disclosed, which was generated from esterification between the in situ generated HSO4- and MeOH, a rate-limiting step in the process. More importantly, the selectivity-controlling step was represented by the subsequent nucleophilic displacement between MeOSO3- and aldehydes. The ionic oxidant la ((NH4)(2)S2O8) with more N-H numbers in the cation, as compared with lc ((n-Bu4N)(2)S2O8) and Id ((PyH)(2)S2O8), has better performance in the oxidative esterification of aldehydes.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1021/acs.joc.6b02775
收录类别SCI
语种英语
关键词[WOS]AEROBIC OXIDATION ; CATALYZED ALDEHYDE ; HYDROGEN-PEROXIDE ; AQUEOUS-SOLUTIONS ; ORGANIC-COMPOUNDS ; BOND ACTIVATION ; RATE CONSTANTS ; ESTERIFICATION ; ALCOHOLS ; PEROXYDISULFATE
WOS研究方向Chemistry
WOS类目Chemistry, Organic
项目资助者973 Program(2015CB251401) ; Key Program of National Natural Science Foundation of China(91434203) ; National Natural Science Foundation of China(21476240 ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; CAS 100-Talent Program ; 21406230)
WOS记录号WOS:000394472900033
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22102
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Guo, Ya-Fei,Mahmood, Sajid,Xu, Bao-Hua,et al. Oxidation of Aromatic Aldehydes to Esters: A Sulfate Radical Redox System[J]. JOURNAL OF ORGANIC CHEMISTRY,2017,82(3):1591-1599.
APA Guo, Ya-Fei,Mahmood, Sajid,Xu, Bao-Hua,Yao, Xiao-Qian,He, Hong-Yan,&Zhang, Suo-Jiang.(2017).Oxidation of Aromatic Aldehydes to Esters: A Sulfate Radical Redox System.JOURNAL OF ORGANIC CHEMISTRY,82(3),1591-1599.
MLA Guo, Ya-Fei,et al."Oxidation of Aromatic Aldehydes to Esters: A Sulfate Radical Redox System".JOURNAL OF ORGANIC CHEMISTRY 82.3(2017):1591-1599.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Guo, Ya-Fei]的文章
[Mahmood, Sajid]的文章
[Xu, Bao-Hua]的文章
百度学术
百度学术中相似的文章
[Guo, Ya-Fei]的文章
[Mahmood, Sajid]的文章
[Xu, Bao-Hua]的文章
必应学术
必应学术中相似的文章
[Guo, Ya-Fei]的文章
[Mahmood, Sajid]的文章
[Xu, Bao-Hua]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。