CAS OpenIR  > 研究所(批量导入)
酸性离子液体催化丁烯酯化反应制备乙酸仲丁酯
王傲运; 赵国英; 杨飞飞; 刘方方
2016
Source Publication过程工程学报
Issue4Pages:"667-672"
Abstract

采用两步法合成了[Bmim]HSO_4,[Bmim]Sb F6,Bmim]PF6,[BSmim]HSO_4,[BSmim]CF_3SO_3,[BSN222]H_2PW_12O_40,[Ph3PSO3H]HSO_4等离子液体,以离子液体及离子液体/酸性无机盐为催化剂,在90℃、混合碳四:乙酸体积比18:5、乙酸:催化剂摩尔比2、反应时间4 h条件下,催化丁烯与乙酸的酯化反应.结果表明,以[Ph_3PSO_3H]HSO_4为催化剂时,丁烯转化率、乙酸仲丁酯的选择性和收率分别达88.8%,100.0%和88.8%,远高于以浓H_2SO_4催化的转化率(73.5%)、选择性(77.7%)和收率(57....

Keyword离子液体 催化剂 乙酸丁酯 循环 转化率 丁烯
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22273
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
王傲运,赵国英,杨飞飞,等. 酸性离子液体催化丁烯酯化反应制备乙酸仲丁酯[J]. 过程工程学报,2016(4):"667-672".
APA 王傲运,赵国英,杨飞飞,&刘方方.(2016).酸性离子液体催化丁烯酯化反应制备乙酸仲丁酯.过程工程学报(4),"667-672".
MLA 王傲运,et al."酸性离子液体催化丁烯酯化反应制备乙酸仲丁酯".过程工程学报 .4(2016):"667-672".
Files in This Item:
File Name/Size DocType Version Access License
酸性离子液体催化丁烯酯化反应制备乙酸仲丁(599KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[王傲运]'s Articles
[赵国英]'s Articles
[杨飞飞]'s Articles
Baidu academic
Similar articles in Baidu academic
[王傲运]'s Articles
[赵国英]'s Articles
[杨飞飞]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[王傲运]'s Articles
[赵国英]'s Articles
[杨飞飞]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.