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碱性体系t-BAMBP萃取微量铷及热力学函数研究
尤志刚; 王舒娅; 李吉生; 李波; 段东平; 张啟云; 郑红
2016
Source Publication盐湖研究
Issue1Pages:"38-42"
Abstract

通过对4-叔丁基-2-(α-甲苄基)苯酚(t-BAMBP)萃取微量铷的性能的研究,详细考察了稀释剂、碱度和温度对萃取的影响。实验结果表明,在260#溶剂油体系中,铷的分配比较之在环己烷体系和四氯化碳体系高;强碱性环境和低温条件有利于铷的萃取。同时通过斜率法和饱和法确定了萃合物组成为RORb·ROH,并研究了萃取过程的热焓、吉布斯自由能及熵变等基础热力学性质,结果表明该萃取反应为放热反应,萃取过程熵减。

Keyword T-bambp 萃取 热力学函数
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22445
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
尤志刚,王舒娅,李吉生,等. 碱性体系t-BAMBP萃取微量铷及热力学函数研究[J]. 盐湖研究,2016(1):"38-42".
APA 尤志刚.,王舒娅.,李吉生.,李波.,段东平.,...&郑红.(2016).碱性体系t-BAMBP萃取微量铷及热力学函数研究.盐湖研究(1),"38-42".
MLA 尤志刚,et al."碱性体系t-BAMBP萃取微量铷及热力学函数研究".盐湖研究 .1(2016):"38-42".
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