| Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process | |
| Deng, Jie1; Xu, Bao-Hua2; Wang, Yao-Feng2; Mo, Xian-En2; Zhang, Rui1; Li, You2; Zhang, Suo-Jiang2 | |
| 2017-05-21 | |
| Source Publication | CATALYSIS SCIENCE & TECHNOLOGY
 |
| ISSN | 2044-4753 |
| Volume | 7Issue:10Pages:2065-2073 |
| Abstract | A highly efficient synthesis of isosorbide from sorbitol was developed using Bronsted acidic ionic liquids (BILs) as the catalyst for the first time. The structure-performance relationship was discussed extensively and a proper value of the Gutmann acceptor number (AN) rather than the inherent of acidity was found to be essential for an optimized yield of isosorbide. In addition, the excellent behavior of preferred BIL-4 in the consecutive recycling tests renders the construction of a continuous process probable. Systematic optimization demonstrated that a yield of 82% of isosorbide with a purity of 99.3% could be reached at balance. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c7cy00512a |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | 1-butyl-3-methylimidazolium Hydrogen Sulfate ; Conversion ; Efficient ; Cellulose ; Hexitols ; Fructose ; Isomerization ; Chemistry ; Mechanism ; Cations |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Physical |
| Funding Organization | National Basic Research Program of China (973 Program)(2015CB251401) ; National Natural Science Foundation of China(21476240 ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; Shanghai education commission key projects of scientific research and innovation(14ZZ061) ; CAS (Chinese Academy of Sciences) 100-Talent Program ; Key Research Program of Frontier Sciences, CAS(QYZDY-SSW-JSCo11 ; 21606238 ; QYZDY-SSW-JSC011) ; 21374029) |
| WOS ID | WOS:000401907700012 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/22528 |
| Collection | 多相复杂系统国家重点实验室 |
| Affiliation | 1.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Deng, Jie,Xu, Bao-Hua,Wang, Yao-Feng,et al. Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(10):2065-2073. |
| APA | Deng, Jie.,Xu, Bao-Hua.,Wang, Yao-Feng.,Mo, Xian-En.,Zhang, Rui.,...&Zhang, Suo-Jiang.(2017).Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process.CATALYSIS SCIENCE & TECHNOLOGY,7(10),2065-2073. |
| MLA | Deng, Jie,et al."Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process".CATALYSIS SCIENCE & TECHNOLOGY 7.10(2017):2065-2073. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Bronsted acidic ioni（1714KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text | |
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