Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds | |
Ren, Tian-Lu1,2; Xu, Bao-Hua1,2; Mahmood, Sajid1,2; Sun, Ming-Xue3; Zhang, Suo-Jiang1,2 | |
2017-05-18 | |
Source Publication | TETRAHEDRON
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ISSN | 0040-4020 |
Volume | 73Issue:20Pages:2943-2948 |
Abstract | A protocol for the cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds with carboxylic acids was developed in this work. Mechanistic studies revealed that C(sp(3))-H bond activation in the hydrocarbon was the turnover-limiting step and the in-situ formed [Co(III)]Ot-Bu did not engage in hydrogen atom abstraction (HAA) of a C H bond. This protocol was successfully incorporated into a synthetic pathway to beta-damascenone that avoided the use of NBS. (C) 2017 Elsevier Ltd. All rights reserved. |
Keyword | Cobalt Oxidative Esterification c(Sp(3))-h Bond Activation Carboxylic Acid Peroxide |
Subtype | Article |
WOS Headings | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.tet.2017.04.002 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | Metal-free Conditions ; Allylic Oxidation ; Butyl Hydroperoxide ; Aromatic-aldehydes ; Carboxylic-acids ; Beta-damascenone ; Benzylic Esters ; Cyclic Ethers ; Olefins ; Activation |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Organic |
Funding Organization | National Key Projects for Fundamental Research and Development of China(2016YFB0601303) ; National Natural Science Foundation of China(21476240) ; Key Program of National Natural Science Foundation of China(91434203) ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; CAS (Chinese Academy of Sciences) 100-Talent Program |
WOS ID | WOS:000401210200012 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/22537 |
Collection | 多相复杂系统国家重点实验室 |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.Henan Univ, Henan Engn Res Ctr Resource & Energy Recovery Was, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China |
Recommended Citation GB/T 7714 | Ren, Tian-Lu,Xu, Bao-Hua,Mahmood, Sajid,et al. Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds[J]. TETRAHEDRON,2017,73(20):2943-2948. |
APA | Ren, Tian-Lu,Xu, Bao-Hua,Mahmood, Sajid,Sun, Ming-Xue,&Zhang, Suo-Jiang.(2017).Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds.TETRAHEDRON,73(20),2943-2948. |
MLA | Ren, Tian-Lu,et al."Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds".TETRAHEDRON 73.20(2017):2943-2948. |
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Cobalt-catalyzed oxi(697KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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