| Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds | |
| Ren, Tian-Lu1,2; Xu, Bao-Hua1,2; Mahmood, Sajid1,2; Sun, Ming-Xue3; Zhang, Suo-Jiang1,2 | |
| 2017-05-18 | |
| Source Publication | TETRAHEDRON
 |
| ISSN | 0040-4020 |
| Volume | 73Issue:20Pages:2943-2948 |
| Abstract | A protocol for the cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds with carboxylic acids was developed in this work. Mechanistic studies revealed that C(sp(3))-H bond activation in the hydrocarbon was the turnover-limiting step and the in-situ formed [Co(III)]Ot-Bu did not engage in hydrogen atom abstraction (HAA) of a C H bond. This protocol was successfully incorporated into a synthetic pathway to beta-damascenone that avoided the use of NBS. (C) 2017 Elsevier Ltd. All rights reserved. |
| Keyword | Cobalt Oxidative Esterification c(Sp(3))-h Bond Activation Carboxylic Acid Peroxide |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.tet.2017.04.002 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | Metal-free Conditions ; Allylic Oxidation ; Butyl Hydroperoxide ; Aromatic-aldehydes ; Carboxylic-acids ; Beta-damascenone ; Benzylic Esters ; Cyclic Ethers ; Olefins ; Activation |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Organic |
| Funding Organization | National Key Projects for Fundamental Research and Development of China(2016YFB0601303) ; National Natural Science Foundation of China(21476240) ; Key Program of National Natural Science Foundation of China(91434203) ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; CAS (Chinese Academy of Sciences) 100-Talent Program |
| WOS ID | WOS:000401210200012 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/22537 |
| Collection | 多相复杂系统国家重点实验室 |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.Henan Univ, Henan Engn Res Ctr Resource & Energy Recovery Was, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China |
| Recommended Citation GB/T 7714 | Ren, Tian-Lu,Xu, Bao-Hua,Mahmood, Sajid,et al. Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds[J]. TETRAHEDRON,2017,73(20):2943-2948. |
| APA | Ren, Tian-Lu,Xu, Bao-Hua,Mahmood, Sajid,Sun, Ming-Xue,&Zhang, Suo-Jiang.(2017).Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds.TETRAHEDRON,73(20),2943-2948. |
| MLA | Ren, Tian-Lu,et al."Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds".TETRAHEDRON 73.20(2017):2943-2948. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Cobalt-catalyzed oxi（697KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment