湿法冶金清洁生产技术国家工程实验室知识库

Direct electro-reduction of mixed powders of chromium oxide (Cr2O3) and nickel oxide (NiO) to the intermetallic compound Cr1.12Ni2.88 was successfully demonstrated in CaCl2 molten salt at 900 degrees C. The reduction mechanism was investigated by cyclic voltammetry using a metallic cavity electrode (MCE) as well as the characterizations of some partially electrolyzed products and Ni-Cr alloy prepared from constant voltage electrolysis by terminating the reduction process after different times, which were characterized by means of XRD and SEM et al. It was found that the reduction starts with the formation of Ni metal, accompanied with the formation of an intermediate product CaCr2O4. Then, the intermediate product CaCr2O4 is further electro-reduced to Cr, which is directly alloyed with the newly-formed Ni to form the Ni-Cr intermetallic compound. At the same time, pure Cr phase could not be detected by the XRD or EDXA when the Cr content is relatively low in the NiO-Cr2O3 mixture. Intermetallic compound with the target stoichiometry containing 6000 ppm oxygen is obtained after 4 h electro-reduction in CaCl2 molten salt at 900 degrees C. (C) 2017 The Electrochemical Society. All rights reserved.