CAS OpenIR  > 多相复杂系统国家重点实验室
Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether
Chen, Shengxin1,2; Liu, Ruixia2; Li, Yajing2,3; Zhang, Ruirui2; Zhao, Cong2; Tang, Hongguo2; Qiao, Congzhen1; Zhang, Suojiag2
2017-06-01
Source PublicationCATALYSIS COMMUNICATIONS
ISSN1566-7367
Volume96Pages:69-73
AbstractThe relationship of basicity and hydrogen bond with catalytic performance was investigated in synthesis of propylene glycol methyl ether (PGME) catalyzed by various ILs ([Emim] [OAC], [Bmim] [OM], [N-2222] [OAC], [EtOH111 [OAC], [N-4444]Br, [Bmim] [N(CN)(2)], [Bmim]Br, [Bmim] [PF6]). The basicity and Kamlet-Taft parameters of each catalyst were evaluated by UV visible spectroscopy. It was found the catalytic performance is the synergistic effect of basicity and hydrogen bond donating ability in the synthesis of PGME from PO and CH3OH, which is quite different from the conventional basic catalytic mechanism.
KeywordIonic Liquids Hydrogen Bond Basicity Propylene Oxide Etherification Propylene Glycol Methyl Ether
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.catcom.2017.03.018
Indexed BySCI
Language英语
WOS KeywordSOLVENT PROPERTIES ; SOLID BASE ; OXIDE ; METHANOL ; 1-METHOXY-2-PROPANOL
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationOne Hundred Talent Program of CAS ; National Natural Science Foundation of China Petroleum & Chemical Corporation Joint Fund(U1662129) ; Key Program of National Natural Science Foundation of China(91434203) ; Key Research Program of Frontier Sciences, CAS(QYZDY-SSW-JSC011) ; Fund of State Key Laboratory of Multiphase Complex Systems, IPE, CAS(MPCS-2015-A-05)
WOS IDWOS:000401218700016
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22543
Collection多相复杂系统国家重点实验室
Affiliation1.Henan Univ, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China
2.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn,Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Guangxi Univ, Coll Chem & Chem Engn, Nanning 530004, Peoples R China
Recommended Citation
GB/T 7714
Chen, Shengxin,Liu, Ruixia,Li, Yajing,et al. Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether[J]. CATALYSIS COMMUNICATIONS,2017,96:69-73.
APA Chen, Shengxin.,Liu, Ruixia.,Li, Yajing.,Zhang, Ruirui.,Zhao, Cong.,...&Zhang, Suojiag.(2017).Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether.CATALYSIS COMMUNICATIONS,96,69-73.
MLA Chen, Shengxin,et al."Relationship of basicity and hydrogen bond properties of ionic liquids with its catalytic performance: Application to synthesis of propylene glycol methyl ether".CATALYSIS COMMUNICATIONS 96(2017):69-73.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Chen, Shengxin]'s Articles
[Liu, Ruixia]'s Articles
[Li, Yajing]'s Articles
Baidu academic
Similar articles in Baidu academic
[Chen, Shengxin]'s Articles
[Liu, Ruixia]'s Articles
[Li, Yajing]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Chen, Shengxin]'s Articles
[Liu, Ruixia]'s Articles
[Li, Yajing]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.