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A study of thermal behavior of cesium phosphate
Zhang, GL; Peng, ZJ; Li, CS
MAY
发表期刊JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN1388-6150
卷号124页码:1063
摘要Cesium phosphates with different Cs/P molar ratios were prepared by a solution evaporation method. X-ray powder diffraction, thermogravimetric, and differential thermal analyses were performed in order to reveal the chemical transformation and phase compositions which take place during the heating of the mixtures Cs2CO3/(NH4)(2)HPO4 and CsNO3/(NH4)(2)HPO4 as well as individual compound. The effects of the Cs/P molar ratio, Cs source and treatment temperature on thermal behavior of the cesium phosphates were investigated. The results showed that different reactions take place with molar ratio from 1/2 to 3/1. Meanwhile, the thermostability of Cs2CO3 and CsNO3 intimately affects the phase composition and phase transition during heating process. However, for all the Cs-P oxides samples, the crystallinity was decreased differently after higher temperature treatment.
关键词Alpha-zirconium Phosphate Acrylic-acid Lactic-acid Oxidative Dehydrogenation Catalytic Performance Phase-transition Isobutyric Acid Iron Phosphate Csh2po4 Dehydration
WOS标题词Thermodynamics ; Chemistry
DOI10.1007/s10973-015-5192-x
WOS记录号WOS:000373576600052
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文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22570
专题研究所(批量导入)
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GB/T 7714
Zhang, GL,Peng, ZJ,Li, CS. A study of thermal behavior of cesium phosphate[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
APA Zhang, GL,Peng, ZJ,&Li, CS.
MLA Zhang, GL,et al."A study of thermal behavior of cesium phosphate".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 124
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