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Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts
Guo, Xinpeng1,2; Yang, Dan1; Zuo, Cuncun1; Peng, Zhijian2; Li, Chunshan1; Zhang, Suojiang1
2017-05-24
发表期刊INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
卷号56期号:20页码:5860-5871
摘要Vanadium phosphorus oxide (VPO) catalysts were developed for the aldol condensation of methyl acetate (MeOAC) with formaldehyde (HCHO) to methyl acrylate (MA). The influence of P/V ratio on catalytic activity and selectivity was revealed and optimized with a fixed bed reactor. The controllable preparation of VPO catalyst was reached, and the influence of carrier gas on the resistance of carbon deposition was also systematically investigated. Response surface methodology (RSM) with three independent variables of molar ratio of MeOAC to HCHO, space velocity, and reaction temperature was employed to optimize MA yield with VPO catalysts. The high value of R-squared presented a reasonable correlation of regression model to the experimental data. Lastly, the kinetics of aldol condensation to produce MA over VPO catalyst was studied.
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1021/acs.iecr.7b01212
收录类别SCI
语种英语
关键词[WOS]RESPONSE-SURFACE METHODOLOGY ; N-BUTANE OXIDATION ; PHASE ALDOL CONDENSATION ; P-O CATALYSTS ; VPO CATALYSTS ; ACETIC-ACID ; BIFUNCTIONAL CATALYST ; PHOSPHATE CATALYSTS ; SELECTIVE OXIDATION ; BIODIESEL SYNTHESIS
WOS研究方向Engineering
WOS类目Engineering, Chemical
项目资助者National Science Fund for Excellent Young Scholars(21422607) ; National key R D program(2016YFB0601303) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH022)
WOS记录号WOS:000402498900010
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被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22652
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Clean & Efficient Coking Technol, Beijing Key Lab Ion Liquids Clean Proc,State Key, Beijing 100190, Peoples R China
2.China Univ Geosci, Sch Engn & Technol, Beijing 100083, Peoples R China
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Guo, Xinpeng,Yang, Dan,Zuo, Cuncun,et al. Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2017,56(20):5860-5871.
APA Guo, Xinpeng,Yang, Dan,Zuo, Cuncun,Peng, Zhijian,Li, Chunshan,&Zhang, Suojiang.(2017).Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,56(20),5860-5871.
MLA Guo, Xinpeng,et al."Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 56.20(2017):5860-5871.
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