CAS OpenIR  > 多相复杂系统国家重点实验室
Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts
Guo, Xinpeng1,2; Yang, Dan1; Zuo, Cuncun1; Peng, Zhijian2; Li, Chunshan1; Zhang, Suojiang1
2017-05-24
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume56Issue:20Pages:5860-5871
Abstract

Vanadium phosphorus oxide (VPO) catalysts were developed for the aldol condensation of methyl acetate (MeOAC) with formaldehyde (HCHO) to methyl acrylate (MA). The influence of P/V ratio on catalytic activity and selectivity was revealed and optimized with a fixed bed reactor. The controllable preparation of VPO catalyst was reached, and the influence of carrier gas on the resistance of carbon deposition was also systematically investigated. Response surface methodology (RSM) with three independent variables of molar ratio of MeOAC to HCHO, space velocity, and reaction temperature was employed to optimize MA yield with VPO catalysts. The high value of R-squared presented a reasonable correlation of regression model to the experimental data. Lastly, the kinetics of aldol condensation to produce MA over VPO catalyst was studied.

SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1021/acs.iecr.7b01212
Indexed BySCI
Language英语
WOS KeywordResponse-surface Methodology ; N-butane Oxidation ; Phase Aldol Condensation ; P-o Catalysts ; Vpo Catalysts ; Acetic-acid ; Bifunctional Catalyst ; Phosphate Catalysts ; Selective Oxidation ; Biodiesel Synthesis
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Science Fund for Excellent Young Scholars(21422607) ; National key R D program(2016YFB0601303) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH022)
WOS IDWOS:000402498900010
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22652
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Clean & Efficient Coking Technol, Beijing Key Lab Ion Liquids Clean Proc,State Key, Beijing 100190, Peoples R China
2.China Univ Geosci, Sch Engn & Technol, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Guo, Xinpeng,Yang, Dan,Zuo, Cuncun,et al. Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2017,56(20):5860-5871.
APA Guo, Xinpeng,Yang, Dan,Zuo, Cuncun,Peng, Zhijian,Li, Chunshan,&Zhang, Suojiang.(2017).Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,56(20),5860-5871.
MLA Guo, Xinpeng,et al."Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 56.20(2017):5860-5871.
Files in This Item:
File Name/Size DocType Version Access License
Catalysts, Process O(2275KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Guo, Xinpeng]'s Articles
[Yang, Dan]'s Articles
[Zuo, Cuncun]'s Articles
Baidu academic
Similar articles in Baidu academic
[Guo, Xinpeng]'s Articles
[Yang, Dan]'s Articles
[Zuo, Cuncun]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Guo, Xinpeng]'s Articles
[Yang, Dan]'s Articles
[Zuo, Cuncun]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.