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Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole
Li, Zhimin1; Yuan, Yutao1,2; Zhang, Yanqiang1; Liu, Long1,3; Zhang, Suojiang1
2017-05-18
发表期刊ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
卷号643期号:10页码:647-652
摘要Energetic copper(II) complexes based on 3,5-dinitrobenzoic acid (HDNBA) and 1,5-diaminotetrazole (DAT), Cu(DNBA)(2)(H2O)(2) (1) and Cu(DAT)(2)(DNBA)(2) (2) were synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal and powder X-ray diffraction. In both complexes, Cu-II was coordinated to a plane tetragon, by four oxygen atoms from two DNBA(-) ions and two coordinated H2O molecules for 1, and by two oxygen atoms and two nitrogen atoms from different DNBA(-) ions and DAT ligands for 2. Differential scanning calorimetry (DSC) and thermogravimetry (TG) analyses were employed to measure the thermal decomposition processes and non-isothermal kinetics parameters of the complexes. The thermal decomposition onset temperatures of 1 and 2 are 321 and 177 degrees C. The apparent activation energies of the first exothermic decomposition peaks of 1 and 2 are 247.2 and 185.2 kJmol(-1). Both 1 (35 J, > 360 N) and 2 (12.5 J, > 360 N) are less sensitive than RDX. The catalytic effects on the decomposition of ammonium perchlorate (AP) of 1 and 2 were studied by DSC. All results supported the potential applications of the energetic complexes as additives of solid rocket propellants.
关键词1 Copper 5-diaminotetrazole 3 Energetic Complexes 5-dinitrobenzoic Acid Additives
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/zaac.201700086
收录类别SCI
语种英语
关键词[WOS]NITROGEN-RICH ; PHYSICOCHEMICAL PROPERTIES ; SENSITIVITY ; SALTS ; DENSITY
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
项目资助者National Natural Science Foundation of China(21376252 ; China Postdoctoral Science Foundation(2015M571128) ; Hong Kong Scholars Program(XJ2015043) ; 21576270 ; 21676281)
WOS记录号WOS:000402418600005
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22653
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
3.Inst Proc Engn, Lab Particle Sci & Engn, Beijing 100190, Peoples R China
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Li, Zhimin,Yuan, Yutao,Zhang, Yanqiang,et al. Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2017,643(10):647-652.
APA Li, Zhimin,Yuan, Yutao,Zhang, Yanqiang,Liu, Long,&Zhang, Suojiang.(2017).Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,643(10),647-652.
MLA Li, Zhimin,et al."Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 643.10(2017):647-652.
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