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Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers
Ayodele, Olubunmi O.1,2,3; Dawodu, Folasegun A.2; Yan, Dongxia1; Dong, Huixian1; Xin, Jiayu1; Zhang, Suojiang1
2017-05-23
Source PublicationCHEMISTRYSELECT
ISSN2365-6549
Volume2Issue:15Pages:4219-4225
Abstract

Conversion of biomass into a suitable fuel involves series of chemical transformation including C-C coupling and hydrodeoxygenation reactions. Here, we have employed coupling reaction to a biomass-derived angelica lactone in the presence of mild alkaline catalysts, K2CO3 to obtain dimers and trimers in appropriate quantities. Hydrodeoxygenation of these molecules over carbon-supported noble metal catalysts was performed. Subsequently, the effect of operating parameters such as hydrogen pressure, temperature and reaction time on the hydrodeoxygenation of di/trimers were fully optimized and liquids suitable for gasoline application were obtained. This process has the potential of scale-up since the raw materials can easily be obtained from freely available biomass and the technology involved in carbon-carbon coupling and hydrodeoxygenation is well known.

KeywordAngelica Lactone Biomass C-c Coupling Catalysts Hydrodeoxygenation
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1002/slct.201700451
Indexed BySCI
Language英语
WOS KeywordHigh-quality Diesel ; Transportation Fuels ; Gamma-valerolactone ; Carbon-dioxide ; Biomass ; Liquid ; Hydrocarbons ; Conversion ; Hydrogen ; Alkanes
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationInternational S&T Cooperation Program of China(2014DFA61670) ; National Natural Science Foundation of China(21576269 ; BIC, Chinese Academy of Sciences(GJHZ201306) ; World Academy of Sciences (TWAS) ; Chinese Academy of Sciences (CAS) ; 21276260 ; 21210006)
WOS IDWOS:000402286000008
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22658
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Ibadan, Dept Ind Chem, Ibadan, Oyo State, Nigeria
3.Forestry Res Inst Nigeria, Dept Forest Prod Dev & Utilizat, Ibadan, Oyo State, Nigeria
Recommended Citation
GB/T 7714
Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,et al. Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers[J]. CHEMISTRYSELECT,2017,2(15):4219-4225.
APA Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,Dong, Huixian,Xin, Jiayu,&Zhang, Suojiang.(2017).Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers.CHEMISTRYSELECT,2(15),4219-4225.
MLA Ayodele, Olubunmi O.,et al."Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers".CHEMISTRYSELECT 2.15(2017):4219-4225.
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