CAS OpenIR  > 研究所(批量导入)
Affinity regulation of the NH3 + H2O system by ionic liquids with molecular interaction analysis
Huang, Weijia1; Zheng, Danxing2; Xia, Changxing3; Feng, Lejun1; Dong, Li4; Jiang, Peixue1
2017-06-28
发表期刊PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN1463-9076
卷号19期号:24页码:16242-16250
摘要

This work proposed using an adequate ionic liquid (IL) to weaken the affinity between NH3 and H2O as a potential solution to the issue of high-energy consumption involved in separating NH3 gas from liquid H2O. Two quaternary phosphonium-based ILs were selected according to an optimized regulation strategy. The regulation effects of the ILs were evaluated by the vapor-liquid equilibrium property of the NH3 + H2O + IL systems, and were compared with the regulation effects of traditional additives. The results showed that the expected effects were achieved by adding ILs. The regulation mechanisms of different strategies were discussed with respect to the molecular structure and chemical equilibrium for the first time limited to the authors' latest literature review. Finally, the IR spectra of the NH3 + H2O + IL systems were acquired and analyzed to verify the interactions of the ILs with NH3 and H2O.

文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c7cp01757j
收录类别SCI
语种英语
关键词[WOS]Temperature Ionic Liquids ; Potassium Hydroxide ; Vapor-pressure ; Plus Water ; Ammonia Absorption ; 353.15 k ; Equilibrium ; Solubility ; Mixtures ; Solvents
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
项目资助者National Natural Science Foundation of China(51276010)
WOS记录号WOS:000403965500068
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22699
专题研究所(批量导入)
作者单位1.Tsinghua Univ, Dept Thermal Engn, Beijing 100084, Peoples R China
2.Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
3.Dezhou Shihua Chem Co Ltd, Dezhou 253000, Shandong, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Huang, Weijia,Zheng, Danxing,Xia, Changxing,et al. Affinity regulation of the NH3 + H2O system by ionic liquids with molecular interaction analysis[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2017,19(24):16242-16250.
APA Huang, Weijia,Zheng, Danxing,Xia, Changxing,Feng, Lejun,Dong, Li,&Jiang, Peixue.(2017).Affinity regulation of the NH3 + H2O system by ionic liquids with molecular interaction analysis.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,19(24),16242-16250.
MLA Huang, Weijia,et al."Affinity regulation of the NH3 + H2O system by ionic liquids with molecular interaction analysis".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 19.24(2017):16242-16250.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Affinity regulation (2780KB)期刊论文出版稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Huang, Weijia]的文章
[Zheng, Danxing]的文章
[Xia, Changxing]的文章
百度学术
百度学术中相似的文章
[Huang, Weijia]的文章
[Zheng, Danxing]的文章
[Xia, Changxing]的文章
必应学术
必应学术中相似的文章
[Huang, Weijia]的文章
[Zheng, Danxing]的文章
[Xia, Changxing]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Affinity regulation of the NH3 + H2O system by ionic liquids with molecular interaction analysis.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。