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Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale
Raja, Muhammad Afzal1,2; Chen, Hao3; Zhao, Yongsheng1,2; Zhang, Xiangping1; Zhang, Suojiang1
2017-02-23
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
Volume42Issue:8Pages:4922-4934
Abstract

Retorting oil shale produces shale oil, spent shale, retorting gas and water. On the basis of advantages offered by the fluidized bed retorting technology in comparison with ordinary retorting technologies of oil shale, fluidized bed oil shale retorting process to produce hydrogen and high valued hydrocarbon fuels (HVHFs) products is simulated and analyzed in this work. An integrated process scheme is designed in this work for hydrogenation of shale oil which consists of ebullated-bed catalytic reactor (EBCR) hydrogenation unit and two stage fixed bed catalytic reactors (FBCRs) hydrogenation unit. Four different scenarios are simulated and compared with respect to the end products and the energy efficiencies (HHV %) of the systems. The results indicate that the fourth scenario has least energy efficiency of the system (38.58% (HHV) of oil shale energy is stored in products, 36.13% (HHV) in HVHFs and 2.45% (HHV) in hydrogen) but provides the most important required end products as hydrogen (1.87 wt. %), middle distillate (68.97 wt. % (>80 wt. % diesel)), LPG (1.36 wt. %), naphtha (9.98 wt. %) and LSFO (19.21 wt. %). The whole system is modeled and simulated in the Aspen Plus V8.4 and the results are compatible with the industrial and experimental data. The sensitivity analyses are carried out to show the effects of various key operating parameters on the production of shale oil, retorting gas and hydrogen respectively. (C) 2017,Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

KeywordOil Shale Retorting Modeling Simulation Mass Flow Analysis Energy Flow Analysis
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.ijhydene.2017.01.101
Indexed BySCI
Language英语
WOS KeywordGasification ; Nanoparticles ; Temperature ; Prediction ; Resources ; Petroleum ; Refinery ; Biomass ; Gases ; Yield
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
Funding OrganizationNational Basic Research Program of China(2014CB744306) ; National Natural Science Fund for Distinguished Young Scholars(21425625) ; National Natural Science Foundation of China(21376242) ; External Cooperation Program of BIC, Chinese Academy of Sciences(122111KYS820150017)
WOS IDWOS:000403852600020
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22712
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing, Peoples R China
2.Univ Chinese Acad Sci, Coll Chem & Engn, Beijing 100049, Peoples R China
3.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Raja, Muhammad Afzal,Chen, Hao,Zhao, Yongsheng,et al. Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(8):4922-4934.
APA Raja, Muhammad Afzal,Chen, Hao,Zhao, Yongsheng,Zhang, Xiangping,&Zhang, Suojiang.(2017).Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(8),4922-4934.
MLA Raja, Muhammad Afzal,et al."Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.8(2017):4922-4934.
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