Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale

doi:10.1016/j.ijhydene.2017.01.101

	Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale
	Raja, Muhammad Afzal 1,2; Chen, Hao 3; Zhao, Yongsheng 1,2; Zhang, Xiangping 1; Zhang, Suojiang 1
	2017-02-23
发表期刊	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN	0360-3199
卷号	42 期号:8 页码:4922-4934
摘要	Retorting oil shale produces shale oil, spent shale, retorting gas and water. On the basis of advantages offered by the fluidized bed retorting technology in comparison with ordinary retorting technologies of oil shale, fluidized bed oil shale retorting process to produce hydrogen and high valued hydrocarbon fuels (HVHFs) products is simulated and analyzed in this work. An integrated process scheme is designed in this work for hydrogenation of shale oil which consists of ebullated-bed catalytic reactor (EBCR) hydrogenation unit and two stage fixed bed catalytic reactors (FBCRs) hydrogenation unit. Four different scenarios are simulated and compared with respect to the end products and the energy efficiencies (HHV %) of the systems. The results indicate that the fourth scenario has least energy efficiency of the system (38.58% (HHV) of oil shale energy is stored in products, 36.13% (HHV) in HVHFs and 2.45% (HHV) in hydrogen) but provides the most important required end products as hydrogen (1.87 wt. %), middle distillate (68.97 wt. % (>80 wt. % diesel)), LPG (1.36 wt. %), naphtha (9.98 wt. %) and LSFO (19.21 wt. %). The whole system is modeled and simulated in the Aspen Plus V8.4 and the results are compatible with the industrial and experimental data. The sensitivity analyses are carried out to show the effects of various key operating parameters on the production of shale oil, retorting gas and hydrogen respectively. (C) 2017,Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
关键词	Oil Shale Retorting Modeling Simulation Mass Flow Analysis Energy Flow Analysis
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1016/j.ijhydene.2017.01.101
收录类别	SCI
语种	英语
关键词[WOS]	GASIFICATION ; NANOPARTICLES ; TEMPERATURE ; PREDICTION ; RESOURCES ; PETROLEUM ; REFINERY ; BIOMASS ; GASES ; YIELD
WOS研究方向	Chemistry ; Electrochemistry ; Energy & Fuels
WOS类目	Chemistry, Physical ; Electrochemistry ; Energy & Fuels
项目资助者	National Basic Research Program of China(2014CB744306) ; National Natural Science Fund for Distinguished Young Scholars(21425625) ; National Natural Science Foundation of China(21376242) ; External Cooperation Program of BIC, Chinese Academy of Sciences(122111KYS820150017)
WOS记录号	WOS:000403852600020
引用统计
文献类型	期刊论文
条目标识符	http://ir.ipe.ac.cn/handle/122111/22712
专题	多相复杂系统国家重点实验室
作者单位	1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Engn, Beijing 100049, Peoples R China 3.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Raja, Muhammad Afzal,Chen, Hao,Zhao, Yongsheng,et al. Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(8):4922-4934.
APA	Raja, Muhammad Afzal,Chen, Hao,Zhao, Yongsheng,Zhang, Xiangping,&Zhang, Suojiang.(2017).Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(8),4922-4934.
MLA	Raja, Muhammad Afzal,et al."Process simulation and assessment of hydrogen and high valued hydrocarbon fuels products from oil shale".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.8(2017):4922-4934.