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Preparation of carbon-Ni/MgO-Al2O3 composite catalysts for CO2 reforming of methane
Jin, Lijun1,2; Xie, Tong1; Ma, Bingxue1; Li, Yang1; Hu, Haoquan1
2017-02-23
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
Volume42Issue:8Pages:5047-5055
Abstract

Carbon-Ni/MgO-Al2O3 composite catalysts were prepared using sucrose as carbon precursor and [Ni,Mg,Al]-layered double hydroxide (LDH) as Ni-based catalyst precursor by impregnation method, characterized and used for CO2 reforming of CH4. The results showed that pretreated temperature of LDH, carbonization temperature of composite catalyst precursors and the sucrose/layered double oxide (LDO) mass ratio have obvious effect on the structure and catalytic performances of the resultant composite catalysts. The incorporation of carbon into Ni-based catalyst results in the increase of specific surface area, anti-coke ability, inhibition of Ni particle growth and catalytic stability, but a little decrease in initial activities of catalysts owing to low catalytic activity of the carbon. At an appropriate condition with LDH pretreated temperature of 350 degrees C, carbonization temperature of 800 degrees C and sucrose/LDO ratio of 1.2, the resultant composite catalyst exhibits the best activity and stability. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

KeywordCo2 Reforming Of Ch4 Ni/mgo-al2o3 Sucrose Composite Catalyst Layered Double Hydroxide
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.ijhydene.2016.11.130
Indexed BySCI
Language英语
WOS KeywordLayered Double Hydroxides ; Carbon-dioxide ; Synthesis Gas ; Hydrogen ; Ch4 ; Ni ; Decomposition ; Precursors ; Performance ; Syngas
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
Funding OrganizationCoal-based Low Hydrocarbons by NSFC(U1510101) ; Shanxi Provincial Government(U1510101) ; National Key Research and Development Program of China(2016YFB0600301) ; NSFC(U1503194) ; Xinjiang Provincial Government(U1503194) ; Liaoning Province Education Administration Fund(L2013028) ; State Key Laboratory of Multiphase Complex Systems(MPCS-2014-D-07) ; Fundamental Research Funds for the Central Universities(DUT15LAB09)
WOS IDWOS:000403852600032
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22721
Collection多相复杂系统国家重点实验室
Affiliation1.Dalian Univ Technol, Sch Chem Engn, Inst Coal Chem Engn, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Jin, Lijun,Xie, Tong,Ma, Bingxue,et al. Preparation of carbon-Ni/MgO-Al2O3 composite catalysts for CO2 reforming of methane[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(8):5047-5055.
APA Jin, Lijun,Xie, Tong,Ma, Bingxue,Li, Yang,&Hu, Haoquan.(2017).Preparation of carbon-Ni/MgO-Al2O3 composite catalysts for CO2 reforming of methane.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(8),5047-5055.
MLA Jin, Lijun,et al."Preparation of carbon-Ni/MgO-Al2O3 composite catalysts for CO2 reforming of methane".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.8(2017):5047-5055.
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