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Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times
Jiao, Nianming1,2; Zhang, Yanqiang1,3; Liu, Long1; Shreeve, Jean'ne M.4; Zhang, Suojiang1
2017-07-14
发表期刊JOURNAL OF MATERIALS CHEMISTRY A
ISSN2050-7488
卷号5期号:26页码:13341-13346
摘要In bipropulsion systems, hypergolic ionic liquids with B-H groups, as promising alternatives to toxic hydrazine-based fuels, can improve propulsion performance. A series of borohydride cluster-based salts with excellent hydrolytic and thermal stabilities (T-d > 200 degrees C), and the highest density (1.18 g cm(-3)) of any known borohydride hypergolic ionic liquids were prepared. Upon contact with white fuming nitric acid or N2O4, these new salts have ultra-fast ignition delay times (as low as 1 ms), which is a superior ignition performance. Theoretical studies were employed in order to understand their high stability and good ignition performance.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1039/c7ta04038e
收录类别SCI
语种英语
关键词[WOS]RICH IONIC LIQUIDS ; BORON
WOS研究方向Chemistry ; Energy & Fuels ; Materials Science
WOS类目Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
项目资助者National Key Research and Development Program of China(2016YFB0600903) ; National Natural Science Foundation of China(21376252 ; 21576270 ; 21676281)
WOS记录号WOS:000404618200007
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/22802
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing 100049, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China
4.Univ Idaho, Dept Chem, Moscow, ID 83844 USA
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Jiao, Nianming,Zhang, Yanqiang,Liu, Long,et al. Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(26):13341-13346.
APA Jiao, Nianming,Zhang, Yanqiang,Liu, Long,Shreeve, Jean'ne M.,&Zhang, Suojiang.(2017).Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times.JOURNAL OF MATERIALS CHEMISTRY A,5(26),13341-13346.
MLA Jiao, Nianming,et al."Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times".JOURNAL OF MATERIALS CHEMISTRY A 5.26(2017):13341-13346.
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