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Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times
Jiao, Nianming1,2; Zhang, Yanqiang1,3; Liu, Long1; Shreeve, Jean'ne M.4; Zhang, Suojiang1
2017-07-14
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
ISSN2050-7488
Volume5Issue:26Pages:13341-13346
Abstract

In bipropulsion systems, hypergolic ionic liquids with B-H groups, as promising alternatives to toxic hydrazine-based fuels, can improve propulsion performance. A series of borohydride cluster-based salts with excellent hydrolytic and thermal stabilities (T-d > 200 degrees C), and the highest density (1.18 g cm(-3)) of any known borohydride hypergolic ionic liquids were prepared. Upon contact with white fuming nitric acid or N2O4, these new salts have ultra-fast ignition delay times (as low as 1 ms), which is a superior ignition performance. Theoretical studies were employed in order to understand their high stability and good ignition performance.

SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1039/c7ta04038e
Indexed BySCI
Language英语
WOS KeywordRich Ionic Liquids ; Boron
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
Funding OrganizationNational Key Research and Development Program of China(2016YFB0600903) ; National Natural Science Foundation of China(21376252 ; 21576270 ; 21676281)
WOS IDWOS:000404618200007
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22802
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing 100049, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China
4.Univ Idaho, Dept Chem, Moscow, ID 83844 USA
Recommended Citation
GB/T 7714
Jiao, Nianming,Zhang, Yanqiang,Liu, Long,et al. Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(26):13341-13346.
APA Jiao, Nianming,Zhang, Yanqiang,Liu, Long,Shreeve, Jean'ne M.,&Zhang, Suojiang.(2017).Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times.JOURNAL OF MATERIALS CHEMISTRY A,5(26),13341-13346.
MLA Jiao, Nianming,et al."Hypergolic fuels based on water-stable borohydride cluster anions with ultralow ignition delay times".JOURNAL OF MATERIALS CHEMISTRY A 5.26(2017):13341-13346.
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