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Rapid and productive extraction of high purity cellulose material via selective depolymerization of the lignin-carbohydrate complex at mild conditions
Yang, Jiming1,2; Lu, Xingmei1,2; Liu, Xiaomin1; Xu, Junli1; Zhou, Qing1,2; Zhang, Suojiang1,2
2017-05-07
Source PublicationGREEN CHEMISTRY
ISSN1463-9262
Volume19Issue:9Pages:2234-2243
Abstract

A new green cellulose extraction method - the selective degradation dissolution extraction (SDDE) method based on the [Bmim] Cl-AS (i.e. amino sulfonic acid (AS)) solvent system - was found which could rapidly extract a high yield and purity of cellulose from cornstalk at relatively low temperatures in a remarkably short time. In the SDDE method, the lignin-carbohydrate complex protective layer (LCCPL), which wraps around the cellulose, was selectively depolymerized into small molecules; as a result, the rapid dissolution of lignocellulose biomass and the efficient removal of lignin and hemicellulose from the regenerated material (RM) were successfully achieved. The cellulose content of the RM could reach 99.16 +/- 0.15%, which is the highest purity of cellulose extracted from the lignocellulose biomass in one step by IL solvent systems. The delignification rate could reach 97.56 +/- 0.29% while the hemicellulose was completely removed in only 1 h after the cornstalk powder was dissolved in [Bmim] Cl-AS (the AS content was 1.5 wt%) at 100 degrees C. The result showed that the addition of AS not only improved the purity of cellulose in the RM but also increased its yield. The yield of cellulose increased from 19.94 +/- 0.45% to 71.04 +/- 0.78% after the addition of AS. As the mild fractionation conditions reduced consumption of energy greatly as well as that the additive was cheap and environmentally friendly, the SDDE might be able to provide a feasible path to achieve an efficient cellulose extraction from lignocellulose biomass. In addition, utilization of the lignocellulose biomass mostly focused on the preparation of bioethanol via hydrolysis and fermentation. This work provided an alternative that high purity cellulose derivatives and cellulose composites could be produced from the lignocellulose biomass.

SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c7gc00493a
Indexed BySCI
Language英语
WOS KeywordSolid Acid Catalyst ; Ionic Liquids ; Lignocellulosic Biomass ; Archaeological Woods ; Enzymatic-hydrolysis ; Sulfamic Acid ; State Nmr ; Dissolution ; Efficient ; Pretreatment
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationNational Natural Scientific Fund of China(21210006 ; 21336002 ; 21376242 ; 21476234 ; 21606240)
WOS IDWOS:000400836500025
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/22836
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Beijing Key Lab Ionic Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yang, Jiming,Lu, Xingmei,Liu, Xiaomin,et al. Rapid and productive extraction of high purity cellulose material via selective depolymerization of the lignin-carbohydrate complex at mild conditions[J]. GREEN CHEMISTRY,2017,19(9):2234-2243.
APA Yang, Jiming,Lu, Xingmei,Liu, Xiaomin,Xu, Junli,Zhou, Qing,&Zhang, Suojiang.(2017).Rapid and productive extraction of high purity cellulose material via selective depolymerization of the lignin-carbohydrate complex at mild conditions.GREEN CHEMISTRY,19(9),2234-2243.
MLA Yang, Jiming,et al."Rapid and productive extraction of high purity cellulose material via selective depolymerization of the lignin-carbohydrate complex at mild conditions".GREEN CHEMISTRY 19.9(2017):2234-2243.
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