CAS OpenIR  > 湿法冶金清洁生产技术国家工程实验室
Fischer-Tropsch synthesis in a microchannel reactor using mesoporous silica supported bimetallic Co-Ni catalyst: Process optimization and kinetic modeling
Sun, Yong1; Yang, Gang2,3; Zhang, Lian4; Sun, Zhi5
2017-09-01
Source PublicationCHEMICAL ENGINEERING AND PROCESSING
ISSN0255-2701
Volume119Pages:44-61
Abstract

Fischer-Tropsch (FT) synthesis was carried out in a microchannel reactor under a wide range of operating conditions (e.g. 280-320 degrees C, 10-50 bar, H-2/CO 1-3) using a mesoporous supported bimetallic Co-Ni catalyst. The response surface methodology (RSM) and central composite design (CCD) were employed in determining the optimal condition for light olefin production. Three key operational parameters (e.g. syngas ratio, operational pressure, and reaction temperature) were chosen as independent variables in CCD. A new comprehensive kinetic model assuming separate rate of CI, C-2, C-3 and C-n (n >= 4) by coupling Langmuir-Hinshelwood-Hougen-Watson (LHHW) carbide mechanistic approach together with thermodynamic correction is capable of representing olefm-to-paraffin ratio (O/P ratio) and product distribution at experimental conditions in this microchannel reactor.

KeywordFischer-tropsch Synthesis Bimetallic Co-ni Mesoporous Silica Microchannel Reactor Process Optimization Kinetic Modeling
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1016/j.cep.2017.05.017
Indexed BySCI
Language英语
WOS KeywordFixed-bed Reactor ; Activated Carbon ; Liquid Hydrocarbons ; Slurry Reactor ; Cobalt ; Mechanism ; Methane ; Syngas ; Performance ; Hydrogen
WOS Research AreaEnergy & Fuels ; Engineering
WOS SubjectEnergy & Fuels ; Engineering, Chemical
Funding OrganizationAnpeng high-tech energy-resources Co. Ltd
WOS IDWOS:000406731000006
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23170
Collection湿法冶金清洁生产技术国家工程实验室
Affiliation1.Edith Cowan Univ, Sch Engn, 270 Joondalup Dr, Joondalup, WA 6027, Australia
2.Anpeng High Tech Energy Corp, Beijing, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Coupled Acid & Alkaline Prod Techno, Beijing 100190, Peoples R China
4.Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
5.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Sun, Yong,Yang, Gang,Zhang, Lian,et al. Fischer-Tropsch synthesis in a microchannel reactor using mesoporous silica supported bimetallic Co-Ni catalyst: Process optimization and kinetic modeling[J]. CHEMICAL ENGINEERING AND PROCESSING,2017,119:44-61.
APA Sun, Yong,Yang, Gang,Zhang, Lian,&Sun, Zhi.(2017).Fischer-Tropsch synthesis in a microchannel reactor using mesoporous silica supported bimetallic Co-Ni catalyst: Process optimization and kinetic modeling.CHEMICAL ENGINEERING AND PROCESSING,119,44-61.
MLA Sun, Yong,et al."Fischer-Tropsch synthesis in a microchannel reactor using mesoporous silica supported bimetallic Co-Ni catalyst: Process optimization and kinetic modeling".CHEMICAL ENGINEERING AND PROCESSING 119(2017):44-61.
Files in This Item:
File Name/Size DocType Version Access License
Fischer-Tropsch synt(1963KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Sun, Yong]'s Articles
[Yang, Gang]'s Articles
[Zhang, Lian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Sun, Yong]'s Articles
[Yang, Gang]'s Articles
[Zhang, Lian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Sun, Yong]'s Articles
[Yang, Gang]'s Articles
[Zhang, Lian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.