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Formation of Septuple-Shelled (Co2/3Mn1/3)(Co5/6Mn1/6)(2)O-4 Hollow Spheres as Electrode Material for Alkaline Rechargeable Battery
Zhao, Xiaoxian1; Yu, Ranbo1; Tang, Hongjie2; Mao, Dan2; Qi, Jian2; Wang, Bao2; Zhang, Yu3; Zhao, Huijun4; Hu, Wenping5,6; Wang, Dan2,4
2017-09-13
发表期刊ADVANCED MATERIALS
ISSN0935-9648
卷号29期号:34页码:1700550
摘要

The multishelled (Co2/3Mn1/3)(Co5/6Mn1/6)2O(4) hollow microspheres with controllable shell numbers up to septuple shells are synthesized using developed sequential templating method. Exhilaratingly, the septuple-shelled complex metal oxide hollow microsphere is synthesized for the first time by doping Mn into Co3O4, leading to the change of crystalline rate of precursor. Used as electrode materials for alkaline rechargeable battery, it shows a remarkable reversible capacity (236.39 mAh g(-1) at a current density of 1 A g(-1) by three-electrode system and 106.85 mAh g(-1) at 0.5 A g(-1) in alkaline battery) and excellent cycling performance due to its unique structure.

关键词Complex Metal Oxides Hollow Sphere Rechargeable Batteries Septuple-shelled Sequential Templating Method
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1002/adma.201700550
收录类别SCI
语种英语
关键词[WOS]Lithium-ion Batteries ; Sensitized Solar-cells ; Supercapacitor Electrodes ; Accurate Control ; Energy-storage ; Microspheres ; Performance ; Efficiency ; Capacity ; Graphene
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
项目资助者National Science Fund for Distinguished Young Scholars(21325105) ; National Natural Science Foundation of China(21590795 ; National Key Research and Development Program of China(2016YFB0600903) ; Chinese Academy of Sciences (CAS) Interdisciplinary Innovation Team ; Australian Research Council (ARC)(160104817) ; Youth Innovation Promotion Association of CAS(2017070) ; Foundation for State Key Laboratory of Biochemical Engineering ; Beijing Nova Programme Interdisciplinary Cooperation Project ; 21671016 ; 51472025 ; 51472244 ; 51672274 ; 51661165013 ; 51572261 ; 21401199 ; 51372245)
WOS记录号WOS:000409448300004
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23193
专题生化工程国家重点实验室
作者单位1.Univ Sci & Technol Beijing, Sch Met & Ecol Engn, Dept Phys Chem, 30 Xueyuan Rd, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North 2nd St, Beijing 100190, Peoples R China
3.Beihang Univ, Sch Chem & Environm, Minist Educ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing 100191, Peoples R China
4.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia
5.Tianjin Univ, Dept Chem, Tianjin Key Lab Mol Optoelect Sci, Sch Sci, 92 Weijin Rd, Tianjin 300072, Peoples R China
6.Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, 92 Weijin Rd, Tianjin 300072, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Xiaoxian,Yu, Ranbo,Tang, Hongjie,et al. Formation of Septuple-Shelled (Co2/3Mn1/3)(Co5/6Mn1/6)(2)O-4 Hollow Spheres as Electrode Material for Alkaline Rechargeable Battery[J]. ADVANCED MATERIALS,2017,29(34):1700550.
APA Zhao, Xiaoxian.,Yu, Ranbo.,Tang, Hongjie.,Mao, Dan.,Qi, Jian.,...&Wang, Dan.(2017).Formation of Septuple-Shelled (Co2/3Mn1/3)(Co5/6Mn1/6)(2)O-4 Hollow Spheres as Electrode Material for Alkaline Rechargeable Battery.ADVANCED MATERIALS,29(34),1700550.
MLA Zhao, Xiaoxian,et al."Formation of Septuple-Shelled (Co2/3Mn1/3)(Co5/6Mn1/6)(2)O-4 Hollow Spheres as Electrode Material for Alkaline Rechargeable Battery".ADVANCED MATERIALS 29.34(2017):1700550.
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