Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor
Sun, Yong1; Yang, Gang2; Sun, Zhi3; Zhang, Lian4
2017-07-01
发表期刊ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING
ISSN1932-2135
卷号12期号:4页码:518-526
摘要Fischer-Tropsch synthesis was studied on mesoporous silica supported bimetallic Co-Ni catalyst in the fixed-bed reactor (FBR) and slurry continuous stirred tank reactor (CSTR) under different CO conversions by fixing other process parameters, for example, reaction temperature (300 degrees C), syngas ratio (2), and total pressure (3 MPa). The CO conversion is more sensitive in responding to the decrease of gas hour space velocity in FBR than that in CSTR. The intra-particle diffusional limitation was much improved in the CSTR system during Fischer-Tropsch synthesis due to the smaller particle size of the catalyst. The selectivity of gasoline fraction (C-5-C-13) was larger in CSTR than that in FBR when it was operated at relatively higher CO conversions (65%). The FBR tends to produce higher selectivity of longer-chain hydrocarbons than that in CSTR when the CO conversion was kept at around 22%. The increased 1-olefin selectivity was observed in both FBR and CSTR as CO conversion decrease with the FBR being more sensitive in responding to the CO conversion variation. The CSTR is found to be more effective in increasing light olefin fraction (C-2-C-6) when the CO conversion varies from 22 to 65%. (C) 2017 Curtin University of Technology and John Wiley & Sons, Ltd.
关键词Fischer-tropsch Synthesis Fixed-bed Reactor Slurry Continuous Stirred Tank Reactor Comparative Study
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1002/apj.2094
收录类别SCI
语种英语
关键词[WOS]ACTIVATED CARBON ; MEMBRANE REACTOR ; HEAT-TRANSFER ; CHAIN-LENGTH ; IRON ; OPTIMIZATION ; PERFORMANCE ; WATER ; REMOVAL ; CORNCOB
WOS研究方向Engineering
WOS类目Engineering, Chemical
项目资助者Anpeng High-Tech Energy and Resource-Company
WOS记录号WOS:000409279400001
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23204
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Edith Cowan Univ, Sch Engn, 270 Joondalup Dr, Joondalup, WA 6027, Australia
2.Anpeng Energy Grp, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China
4.Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
推荐引用方式
GB/T 7714
Sun, Yong,Yang, Gang,Sun, Zhi,et al. Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor[J]. ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,2017,12(4):518-526.
APA Sun, Yong,Yang, Gang,Sun, Zhi,&Zhang, Lian.(2017).Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor.ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,12(4),518-526.
MLA Sun, Yong,et al."Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor".ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING 12.4(2017):518-526.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Sun, Yong]的文章
[Yang, Gang]的文章
[Sun, Zhi]的文章
百度学术
百度学术中相似的文章
[Sun, Yong]的文章
[Yang, Gang]的文章
[Sun, Zhi]的文章
必应学术
必应学术中相似的文章
[Sun, Yong]的文章
[Yang, Gang]的文章
[Sun, Zhi]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。