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In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance
Wang, Ze1,2; Zeng, Ying1,2; Lin, Weigang1,2,3; Song, Wenli1,2
2017-08-17
发表期刊INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
卷号42期号:33页码:21040-21047
摘要In-situ hydrodeoxygenation of phenol with aqueous hydrogen donor over supported Ni catalyst was investigated. The supported Ni catalysts exerted very poor performance, if formic acid was used as the hydrogen donor. Catalyst modification by loading K, Na, Mg or La salt could not make the catalyst performance improved. If gaseous hydrogen was used as the hydrogen source the activity of Ni/Al2O3 was pretty high. CO2 was found poisonous to the catalysis, due to the competitive adoption of phenol with CO2. If formic acid was replaced by methanol, the catalyst performance improved remarkably, with major products of cyclohexanone and cyclohexanol. The better effect of methanol enlightened the application of the supported Ni catalyst in in-situ hydrodeoxygenation of phenol. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
关键词In-situ Hydrodeoxygenation Biofuels Catalysis Hydrogen Donor
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.ijhydene.2017.07.053
收录类别SCI
语种英语
关键词[WOS]TEMPERATURE COAL-TAR ; CLEAN LIQUID FUELS ; BIO-OIL ; FAST PYROLYSIS ; GENERATED HYDROGEN ; PD CATALYSTS ; FORMIC-ACID ; BIOMASS ; NITRIDE ; OXIDE
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels
WOS类目Chemistry, Physical ; Electrochemistry ; Energy & Fuels
项目资助者National Natural Science Foundation of China(51476180) ; National Basic Research Program of China (973 Program)(2014CB744304)
WOS记录号WOS:000410010600011
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文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23238
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100190, Peoples R China
3.Tech Univ Denmark, Dept Chem & Biochem Engn, Bldg 229, DK-2800 Lyngby, Denmark
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Wang, Ze,Zeng, Ying,Lin, Weigang,et al. In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(33):21040-21047.
APA Wang, Ze,Zeng, Ying,Lin, Weigang,&Song, Wenli.(2017).In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(33),21040-21047.
MLA Wang, Ze,et al."In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.33(2017):21040-21047.
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