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High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor
Fu, Zhaolin1,2; Wang, Ze1,2; Lin, Weigang1,2,3; Song, Wenli1,2; Li, Songgeng1,2
2017-10-25
Source PublicationAPPLIED CATALYSIS A-GENERAL
ISSN0926-860X
Volume547Pages:248-255
Abstract

Conversion of furfural to 2-methylfuran over Cu/Al2O3, Ni/Al2O3 and Ni-Cu/Al2O3 catalysts were investigated with formic acid as a hydrogen donor. Ni/Al2O3 showed a high catalytic activity but a moderate selectivity to 2-methylfuran. Contrarily, Cu/Al2O3 showed a low catalytic activity but a high selectivity for carbonyl reduction. Over the bimetallic catalysts Ni-10%Cu/Al2O3, by increasing Ni content, more furfural was converted with the reduction of carbonyl primarily. The effect of reaction solvent and the fraction of formic acid were also studied. The result showed that isopropanol solvent could contribute to the formation of furfuryl alcohol with 96% selectivity through the transfer hydrogenation process. Formic acid could decompose to H-2 and CO2, remarkably promoting the hydrogenolysis of furfuryl alcohol to 2-methylfuran. Finally, 100% conversion and 92 mol% yield of 2-methylfuran could be obtained over 10%Ni-10%Cu/Al2O3. It was attributed to the synergic effect of Ni-Cu metals, with increased affinity for carbonyl reduction.

KeywordFurfural Hydrogenation 2-methylfuran Hydrogen Donor Bimetallic Catalyst
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Life Sciences & Biomedicine
DOI10.1016/j.apcata.2017.09.011
Indexed BySCI
Language英语
WOS KeywordSitu Generated Hydrogen ; Ni-cu Catalysts ; Bio-oil ; Transfer Hydrogenation/hydrogenolysis ; Selective Hydrogenation ; Bimetallic Catalysts ; Phase Hydrogenation ; Pd Catalysts ; Reduction ; Glycerol
WOS Research AreaChemistry ; Environmental Sciences & Ecology
WOS SubjectChemistry, Physical ; Environmental Sciences
Funding OrganizationNational Natural Science Foundation of China(51476180)
WOS IDWOS:000413607100028
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23298
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100190, Peoples R China
3.Tech Univ Denmark, Dept Chem & Biochem Engn, Bldg 229, DK-2800 Lyngby, Denmark
Recommended Citation
GB/T 7714
Fu, Zhaolin,Wang, Ze,Lin, Weigang,et al. High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor[J]. APPLIED CATALYSIS A-GENERAL,2017,547:248-255.
APA Fu, Zhaolin,Wang, Ze,Lin, Weigang,Song, Wenli,&Li, Songgeng.(2017).High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor.APPLIED CATALYSIS A-GENERAL,547,248-255.
MLA Fu, Zhaolin,et al."High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor".APPLIED CATALYSIS A-GENERAL 547(2017):248-255.
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