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High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor
Fu, Zhaolin1,2; Wang, Ze1,2; Lin, Weigang1,2,3; Song, Wenli1,2; Li, Songgeng1,2
2017-10-25
发表期刊APPLIED CATALYSIS A-GENERAL
ISSN0926-860X
卷号547页码:248-255
摘要

Conversion of furfural to 2-methylfuran over Cu/Al2O3, Ni/Al2O3 and Ni-Cu/Al2O3 catalysts were investigated with formic acid as a hydrogen donor. Ni/Al2O3 showed a high catalytic activity but a moderate selectivity to 2-methylfuran. Contrarily, Cu/Al2O3 showed a low catalytic activity but a high selectivity for carbonyl reduction. Over the bimetallic catalysts Ni-10%Cu/Al2O3, by increasing Ni content, more furfural was converted with the reduction of carbonyl primarily. The effect of reaction solvent and the fraction of formic acid were also studied. The result showed that isopropanol solvent could contribute to the formation of furfuryl alcohol with 96% selectivity through the transfer hydrogenation process. Formic acid could decompose to H-2 and CO2, remarkably promoting the hydrogenolysis of furfuryl alcohol to 2-methylfuran. Finally, 100% conversion and 92 mol% yield of 2-methylfuran could be obtained over 10%Ni-10%Cu/Al2O3. It was attributed to the synergic effect of Ni-Cu metals, with increased affinity for carbonyl reduction.

关键词Furfural Hydrogenation 2-methylfuran Hydrogen Donor Bimetallic Catalyst
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine
DOI10.1016/j.apcata.2017.09.011
收录类别SCI
语种英语
关键词[WOS]Situ Generated Hydrogen ; Ni-cu Catalysts ; Bio-oil ; Transfer Hydrogenation/hydrogenolysis ; Selective Hydrogenation ; Bimetallic Catalysts ; Phase Hydrogenation ; Pd Catalysts ; Reduction ; Glycerol
WOS研究方向Chemistry ; Environmental Sciences & Ecology
WOS类目Chemistry, Physical ; Environmental Sciences
项目资助者National Natural Science Foundation of China(51476180)
WOS记录号WOS:000413607100028
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23298
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100190, Peoples R China
3.Tech Univ Denmark, Dept Chem & Biochem Engn, Bldg 229, DK-2800 Lyngby, Denmark
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Fu, Zhaolin,Wang, Ze,Lin, Weigang,et al. High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor[J]. APPLIED CATALYSIS A-GENERAL,2017,547:248-255.
APA Fu, Zhaolin,Wang, Ze,Lin, Weigang,Song, Wenli,&Li, Songgeng.(2017).High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor.APPLIED CATALYSIS A-GENERAL,547,248-255.
MLA Fu, Zhaolin,et al."High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al2O3 catalyst with formic acid as a hydrogen donor".APPLIED CATALYSIS A-GENERAL 547(2017):248-255.
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