CAS OpenIR  > 生化工程国家重点实验室
Construction and self-assembly of beta-cyclodextrin derivative composite Langmuir films: Host-guest reaction and nanostructures
Gao, Yagui1; Jiao, Tifeng1,2; Xing, Ruirui1,3; Zhang, Lexin1; Zhou, Jingxin1; Peng, Qiuming2
2017-11-20
Source PublicationCOLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN0927-7757
Volume533Issue:NOVPages:68-75
Abstract

The design and preparation of functional beta-cyclodextrin-based composite films are of key importance for wide application fields. This study demonstrates a new route to construct composite films by Langmuir-Blodgett (LB) method via cholesterol-modified beta-cyclodextrin derivative (CD-CHOL). The inclusion complex formation of CD-CHOL and azobenzene derivative (N-Azo) at the air/water interface was investigated. It has been found that the interfacial host-guest recognition could easily occur in the in situ formed CD-CHOL/N-Azo composite films and relatively difficult to occur in the ex situ immersed composite films, because there exist host-guest interaction as well as intermolecular hydrogen bonding interaction. The inclusion complex formation was confirmed by changes in the surface pressure-area isotherms, circular dichroism (CD) and UV-vis spectra of the transferred LB films. And the solvent effect of the composite CD-CHOL/N-Azo films was also investigated, indicating that host-guest interaction between N-Azo and CD-CHOL could occur rather in the nonpolar solvent than the polar solvent. The present research work about beta-cyclodextrin-based composite films by LB method may provide new exploration to prepare organized composite films and demonstrate potential applications in many fields.

KeywordComposite Lb Film Self-assembly Beta-cyclodextrin Derivative Host-guest Reaction Nanostructure
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.colsurfa.2017.08.025
Indexed BySCI
Language英语
WOS KeywordAIR/WATER INTERFACE ; INCLUSION COMPLEXES ; SUPRAMOLECULAR CHIRALITY ; GRAPHENE OXIDE ; AMPHIPHILES ; CHOLESTEROL ; FABRICATION ; VESICLES ; HYDROGEL ; SURFACE
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationNational Natural Science Foundation of China(21473153) ; Support Program for the Top Young Talents of Hebei Province ; China Postdoctoral Science Foundation(2015M580214) ; Scientific and Technological Research and Development Program of Qinhuangdao City(201701B004 ; 201502A006)
WOS IDWOS:000413628000009
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23360
Collection生化工程国家重点实验室
Affiliation1.Yanshan Univ, Sch Environm Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Gao, Yagui,Jiao, Tifeng,Xing, Ruirui,et al. Construction and self-assembly of beta-cyclodextrin derivative composite Langmuir films: Host-guest reaction and nanostructures[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2017,533(NOV):68-75.
APA Gao, Yagui,Jiao, Tifeng,Xing, Ruirui,Zhang, Lexin,Zhou, Jingxin,&Peng, Qiuming.(2017).Construction and self-assembly of beta-cyclodextrin derivative composite Langmuir films: Host-guest reaction and nanostructures.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,533(NOV),68-75.
MLA Gao, Yagui,et al."Construction and self-assembly of beta-cyclodextrin derivative composite Langmuir films: Host-guest reaction and nanostructures".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 533.NOV(2017):68-75.
Files in This Item:
File Name/Size DocType Version Access License
Construction and sel(1151KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Gao, Yagui]'s Articles
[Jiao, Tifeng]'s Articles
[Xing, Ruirui]'s Articles
Baidu academic
Similar articles in Baidu academic
[Gao, Yagui]'s Articles
[Jiao, Tifeng]'s Articles
[Xing, Ruirui]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Gao, Yagui]'s Articles
[Jiao, Tifeng]'s Articles
[Xing, Ruirui]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.