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Water Activity and Phase Equilibria Measurements and Model Simulation for the KCl-SrCl2-H2O System at 323.15 K
Han, Haijun1,2; Guo, Lijiang2,3; Li, Dongdong2; Yao, Yan2
2017-11-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN0021-9568
卷号62期号:11页码:3753-3757
摘要

Water activities for the ternary system of KCl-SrCl2-H2O and its sub-binary system SrCl2-H2O were elaborately measured using an isopiestic method at 323.15 K The solubility isotherms for the KCl-SrCl2-H2O system were determined by the isothermal equilibrium method. It is found that the measured isopiestic composition lines for the KCl-SrCl2-H2O system deviated from the Zdanovskii rule, especially at a lower water activity. The Pitzer-Simonson-Clegg model was used to correlate the measured water activity and solubility data, simulate the thermodynamic properties, and predict the solubility of the ternary system. The reliability of the solubility data measured in this work was evaluated by comparing with the solubility isotherms calculated with the Pitzer-Simonson-Clegg model. The measured water activity and solubility results are of great importance for predicting the phase diagram of other multicomponent systems that related to this ternary system.

文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1021/acs.jced.7b00492
收录类别SCI
语种英语
关键词[WOS]Activity-coefficients ; Isopiestic Determination ; Solubility Evaluation ; 25-degrees-c ; Srcl2 ; Nacl ; Mixtures
WOS研究方向Thermodynamics ; Chemistry ; Engineering
WOS类目Thermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical
项目资助者National Natural Science Foundation of China(21406253 ; 21303239)
WOS记录号WOS:000415140900013
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23394
专题研究所(批量导入)
作者单位1.Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
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Han, Haijun,Guo, Lijiang,Li, Dongdong,et al. Water Activity and Phase Equilibria Measurements and Model Simulation for the KCl-SrCl2-H2O System at 323.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2017,62(11):3753-3757.
APA Han, Haijun,Guo, Lijiang,Li, Dongdong,&Yao, Yan.(2017).Water Activity and Phase Equilibria Measurements and Model Simulation for the KCl-SrCl2-H2O System at 323.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,62(11),3753-3757.
MLA Han, Haijun,et al."Water Activity and Phase Equilibria Measurements and Model Simulation for the KCl-SrCl2-H2O System at 323.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 62.11(2017):3753-3757.
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