| Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst | |
| Gao, Junjie1; Zhang, Zailei2,3; An, Xuebin1; Zhang, Yi1 | |
| 2017-12-31 | |
| Source Publication | APPLIED SURFACE SCIENCE
 |
| ISSN | 0169-4332 |
| Volume | 426Issue:DECPages:714-724 |
| Abstract | We designed and synthesized CuO/SnO2/Pd hollow microboxes, which was developed based on pre pared Cu2O cubes coated Pd nanosheets, controlled oxidation of CU2O/Pd, and etching of Cu2O/CuO/Pd by SnCl4 solution. The catalytic property of the Cu2O, Cu2O/SnO2, Cu2O/Pd/SnO2, Cu2O/Pd, Cu2O/CuO/Pd, CuO/SnO2/Pd, CuO, and commercial catalyst for dimethyldichlorosilane synthesis via the Rochow reaction was investigated. As compared to control samples and commercial catalyst, the prepared CuO/Pd/SnO2 hollow microboxes exhibited much higher silicon conversion (76.6%), which is related to the synergistic effect between CuO, Pd and SnO2, and to the distinct catalyst hollow structure which allows the efficient transportation of the reactant molecules to the active component. (C) 2017 Elsevier B.V. All rights reserved. |
| Keyword | Cuo Sno2 Palladium Hollow |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1016/j.apsusc.2017.07.234 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | COPPER-BASED CATALYSTS ; DIMETHYLDICHLOROSILANE SYNTHESIS ; SOLVOTHERMAL SYNTHESIS ; ION BATTERIES ; MICROSPHERES ; PERFORMANCE ; NANOSTRUCTURES ; MICROPARTICLES ; OXIDATION ; SPHERES |
| WOS Research Area | Chemistry ; Materials Science ; Physics |
| WOS Subject | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
| Funding Organization | National Natural Science Foundation of China(21006120 ; 51402299) |
| WOS ID | WOS:000413658200079 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/23398 |
| Collection | 湿法冶金清洁生产技术国家工程实验室 |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China 3.Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Gao, Junjie,Zhang, Zailei,An, Xuebin,et al. Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst[J]. APPLIED SURFACE SCIENCE,2017,426(DEC):714-724. |
| APA | Gao, Junjie,Zhang, Zailei,An, Xuebin,&Zhang, Yi.(2017).Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst.APPLIED SURFACE SCIENCE,426(DEC),714-724. |
| MLA | Gao, Junjie,et al."Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst".APPLIED SURFACE SCIENCE 426.DEC(2017):714-724. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Designed synthesis C（5670KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text | |
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