Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst
Gao, Junjie1; Zhang, Zailei2,3; An, Xuebin1; Zhang, Yi1
2017-12-31
发表期刊APPLIED SURFACE SCIENCE
ISSN0169-4332
卷号426期号:DEC页码:714-724
摘要

We designed and synthesized CuO/SnO2/Pd hollow microboxes, which was developed based on pre pared Cu2O cubes coated Pd nanosheets, controlled oxidation of CU2O/Pd, and etching of Cu2O/CuO/Pd by SnCl4 solution. The catalytic property of the Cu2O, Cu2O/SnO2, Cu2O/Pd/SnO2, Cu2O/Pd, Cu2O/CuO/Pd, CuO/SnO2/Pd, CuO, and commercial catalyst for dimethyldichlorosilane synthesis via the Rochow reaction was investigated. As compared to control samples and commercial catalyst, the prepared CuO/Pd/SnO2 hollow microboxes exhibited much higher silicon conversion (76.6%), which is related to the synergistic effect between CuO, Pd and SnO2, and to the distinct catalyst hollow structure which allows the efficient transportation of the reactant molecules to the active component. (C) 2017 Elsevier B.V. All rights reserved.

关键词Cuo Sno2 Palladium Hollow
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.apsusc.2017.07.234
收录类别SCI
语种英语
关键词[WOS]COPPER-BASED CATALYSTS ; DIMETHYLDICHLOROSILANE SYNTHESIS ; SOLVOTHERMAL SYNTHESIS ; ION BATTERIES ; MICROSPHERES ; PERFORMANCE ; NANOSTRUCTURES ; MICROPARTICLES ; OXIDATION ; SPHERES
WOS研究方向Chemistry ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
项目资助者National Natural Science Foundation of China(21006120 ; 51402299)
WOS记录号WOS:000413658200079
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23398
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
3.Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China
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Gao, Junjie,Zhang, Zailei,An, Xuebin,et al. Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst[J]. APPLIED SURFACE SCIENCE,2017,426(DEC):714-724.
APA Gao, Junjie,Zhang, Zailei,An, Xuebin,&Zhang, Yi.(2017).Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst.APPLIED SURFACE SCIENCE,426(DEC),714-724.
MLA Gao, Junjie,et al."Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst".APPLIED SURFACE SCIENCE 426.DEC(2017):714-724.
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