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Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst
Gao, Junjie1; Zhang, Zailei2,3; An, Xuebin1; Zhang, Yi1
2017-12-31
Source PublicationAPPLIED SURFACE SCIENCE
ISSN0169-4332
Volume426Issue:DECPages:714-724
Abstract

We designed and synthesized CuO/SnO2/Pd hollow microboxes, which was developed based on pre pared Cu2O cubes coated Pd nanosheets, controlled oxidation of CU2O/Pd, and etching of Cu2O/CuO/Pd by SnCl4 solution. The catalytic property of the Cu2O, Cu2O/SnO2, Cu2O/Pd/SnO2, Cu2O/Pd, Cu2O/CuO/Pd, CuO/SnO2/Pd, CuO, and commercial catalyst for dimethyldichlorosilane synthesis via the Rochow reaction was investigated. As compared to control samples and commercial catalyst, the prepared CuO/Pd/SnO2 hollow microboxes exhibited much higher silicon conversion (76.6%), which is related to the synergistic effect between CuO, Pd and SnO2, and to the distinct catalyst hollow structure which allows the efficient transportation of the reactant molecules to the active component. (C) 2017 Elsevier B.V. All rights reserved.

KeywordCuo Sno2 Palladium Hollow
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.apsusc.2017.07.234
Indexed BySCI
Language英语
WOS KeywordCOPPER-BASED CATALYSTS ; DIMETHYLDICHLOROSILANE SYNTHESIS ; SOLVOTHERMAL SYNTHESIS ; ION BATTERIES ; MICROSPHERES ; PERFORMANCE ; NANOSTRUCTURES ; MICROPARTICLES ; OXIDATION ; SPHERES
WOS Research AreaChemistry ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
Funding OrganizationNational Natural Science Foundation of China(21006120 ; 51402299)
WOS IDWOS:000413658200079
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23398
Collection湿法冶金清洁生产技术国家工程实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
3.Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Gao, Junjie,Zhang, Zailei,An, Xuebin,et al. Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst[J]. APPLIED SURFACE SCIENCE,2017,426(DEC):714-724.
APA Gao, Junjie,Zhang, Zailei,An, Xuebin,&Zhang, Yi.(2017).Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst.APPLIED SURFACE SCIENCE,426(DEC),714-724.
MLA Gao, Junjie,et al."Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst".APPLIED SURFACE SCIENCE 426.DEC(2017):714-724.
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