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Solid-Liquid Equilibria for the Glycine-Alcohol-NaCl-H2O System
Ansari, Ziaul Haque1,2; Li, Zhibao1
2017-10-01
Source PublicationJOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN0021-9568
Volume62Issue:10Pages:3551-3560
Abstract

An investigation of the solubility of glycine-alcohol (ethanol/1-propanol)-NaCl-H2O system was carried out by dynamic method over the temperature range from 283.15 to 333.15 K. The studied systems were glycine-alcohol (ethanol/1-propanol)-H2O, glycine-ethanol-NaCl (0.5, 1.0, 2.0 mol.kg(-1) water)-H2O, glycine-1-propanol-NaCl (0.5 mol.kg(-1) water)-H2O, and NaCl-alcohol (ethanol/1-propanol)-glycine (0.25 mol.kg(-1) water)-H2O. The solubilities of glycine and NaCl were found to increase with increasing temperature and decrease with increasing concentration of alcohols. A chemical model was successfully developed based on the mixed solvent electrolyte (MSE) model by regressing experimental and literature solubilities data of glycine in the glycine-ethanol-NaCl-H2O and glycine-1-propanol-H2O systems. New sets of middle range and UNIQUAC interaction parameters were obtained. The average absolute deviation between regressed and experimental values was found to be less than 7%.

SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1021/acs.jced.7b00549
Indexed BySCI
Language英语
WOS KeywordSolvent Electrolyte Systems ; Modeling Phase-equilibria ; Excess Gibbs Energy ; Aqueous-alkanol Solutions ; Partial Molal Properties ; Local Composition Model ; Equation-of-state ; Amino-acids ; High-pressures ; Transport-properties
WOS Research AreaThermodynamics ; Chemistry ; Engineering
WOS SubjectThermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical
Funding OrganizationNational Natural Science Foundation of China(21476235 ; National Basic Research Development Program of China (973 Program)(2013CB632605) ; U1407112)
WOS IDWOS:000413131800057
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23412
Collection湿法冶金清洁生产技术国家工程实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ansari, Ziaul Haque,Li, Zhibao. Solid-Liquid Equilibria for the Glycine-Alcohol-NaCl-H2O System[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2017,62(10):3551-3560.
APA Ansari, Ziaul Haque,&Li, Zhibao.(2017).Solid-Liquid Equilibria for the Glycine-Alcohol-NaCl-H2O System.JOURNAL OF CHEMICAL AND ENGINEERING DATA,62(10),3551-3560.
MLA Ansari, Ziaul Haque,et al."Solid-Liquid Equilibria for the Glycine-Alcohol-NaCl-H2O System".JOURNAL OF CHEMICAL AND ENGINEERING DATA 62.10(2017):3551-3560.
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