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CO2 absorption with ionic liquids at elevated temperatures
Bai, Lu1; Shang, Dawei1; Li, Mengdie1; Dai, Zhongde2; Deng, Liyuan2; Zhang, Xiangping1
2017-11-01
发表期刊JOURNAL OF ENERGY CHEMISTRY
ISSN2095-4956
卷号26期号:5页码:1001-1006
摘要

CO2 capture with ionic liquids (ILs) has attracted many attentions, and most works focused on absorption ability at ambient temperatures, while seldom research was concerned at elevated temperatures. This not only limits the CO2 absorption application at elevated temperature, but also the determination of the operation condition of the CO2 desorption generally occurring at higher temperature. This work mainly reported CO2 solubilities in ILs at elevated temperatures and related properties were also provided. 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ([C-n MIm][Tf-2 N]) ILs were selected as physical absorbents for CO2 capture in this work due to their relative higher CO2 absorption capacities and good thermal stabilities. The long-term stability tests showed that [C-n MIm][Tf-2 N] is thermally stable at 393.15 K for long time. CO2 solubilities in [C-n MIm][Tf-2 N] were systematically determined at temperatures from 353.15 K to 393.15 K. It demonstrated that CO2 solubility obviously increases with the increase of pressure while slightly decreases with increase of temperature. As the length of alkyl chain on the cation increases, CO2 solubility in ILs increases. Additionally, the thermodynamic properties including the Gibbs free energy, enthalpy, and entropy of CO2 were also calculated. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

关键词Ionic Liquids Co2 Capture Elevated Temperature Pre-combustion
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jechem.2017.07.009
收录类别SCI
语种英语
关键词[WOS]Carbon-dioxide Capture ; Physical Solvents ; Solubility ; Anion ; Pressure ; Separation ; Hydrogen
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
项目资助者National Natural Science Foundation of China(21606233 ; National Natural Science Fund for Distinguished Young Scholars(21425625) ; Research Council of Norway through the CLIMIT program(215732) ; 21436010)
WOS记录号WOS:000415598900020
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23430
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Beijing Key Lab Ionic Liquids Clean Proc, Inst Proc Engn,Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Norwegian Univ Sci & Technol NTNU, Dept Chem Engn, N-7491 Trondheim, Norway
推荐引用方式
GB/T 7714
Bai, Lu,Shang, Dawei,Li, Mengdie,et al. CO2 absorption with ionic liquids at elevated temperatures[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(5):1001-1006.
APA Bai, Lu,Shang, Dawei,Li, Mengdie,Dai, Zhongde,Deng, Liyuan,&Zhang, Xiangping.(2017).CO2 absorption with ionic liquids at elevated temperatures.JOURNAL OF ENERGY CHEMISTRY,26(5),1001-1006.
MLA Bai, Lu,et al."CO2 absorption with ionic liquids at elevated temperatures".JOURNAL OF ENERGY CHEMISTRY 26.5(2017):1001-1006.
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