The Importance of Slag Structure to Boron Removal from Silicon during the Refining Process: Insights from Raman and Nuclear Magnetic Resonance Spectroscopy Study
Qian, Guoyu; Wang, Zhi; Gong, Xuzhong; Sun, Liyuan
2017-12-01
发表期刊METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
ISSN1073-5615
卷号48期号:6页码:3239-3250
摘要

Slag structure plays an important role in determining the relative ease of boron removal from silicon. Correlation between slag structure and boron removal thermodynamics was experimentally studied by Raman and nuclear magnetic resonance (NMR) spectroscopy using CaO-SiO2-Na2O slags with different optical basicities (0.6 to 0.71). Optimization of slag depolymerization leads to efficient removal of boron. The extent of nonbridged oxygen content (NBO/T) and boron removal gradually increased with an increase in optical basicity from 0.6 to 0.66: B2O3 derived from boron oxidation captured nonbridging oxygens of Q (0)(Si), Q (1)(Si), and Q (2)(Si), and was incorporated into the silicate network in the form of Q (3)(Si and B). When optical basicity increased to 0.71, NBO/T rapidly increased and boron removal decreased considerably. Quick depolymerization of Q (3)(Si and B) deteriorated the stability of boron. Various structural forms of boron in the silicate network were successfully detected: the BO3 trihedrons B-[3]-3Si, B-[3]-2Si-1NBO, and BO3 (nonring), and the BO4 tetrahedrons BO4 (1B, 3Si) and BO4 (0B, 4Si). BO4 (1B, 3Si) was the main structure contributing to the increase of boron capacity; BO3 (nonring), detected under higher optical basicity conditions, may cause deterioration of boron removal by suppressing its oxidation.

文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1007/s11663-017-1097-3
收录类别SCI
语种英语
关键词[WOS]METALLURGICAL-GRADE SILICON ; SOLID-STATE NMR ; BOROSILICATE GLASSES ; OPTICAL BASICITY ; MOLTEN SILICON ; CAO-SIO2 ; SOLVENT ; B-11 ; PURIFICATION ; BEHAVIOR
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
项目资助者National Natural Science Foundation of China(51422405 ; 51604256)
WOS记录号WOS:000415806100039
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23436
专题湿法冶金清洁生产技术国家工程实验室
作者单位Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
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Qian, Guoyu,Wang, Zhi,Gong, Xuzhong,et al. The Importance of Slag Structure to Boron Removal from Silicon during the Refining Process: Insights from Raman and Nuclear Magnetic Resonance Spectroscopy Study[J]. METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE,2017,48(6):3239-3250.
APA Qian, Guoyu,Wang, Zhi,Gong, Xuzhong,&Sun, Liyuan.(2017).The Importance of Slag Structure to Boron Removal from Silicon during the Refining Process: Insights from Raman and Nuclear Magnetic Resonance Spectroscopy Study.METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE,48(6),3239-3250.
MLA Qian, Guoyu,et al."The Importance of Slag Structure to Boron Removal from Silicon during the Refining Process: Insights from Raman and Nuclear Magnetic Resonance Spectroscopy Study".METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE 48.6(2017):3239-3250.
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