CAS OpenIR  > 湿法冶金清洁生产技术国家工程实验室
High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports
Zhang, Shuangshuang1,6; Oms, Olivier2; Hao, Long4; Liu, Rongji1; Wang, Meng1; Zhang, Yaqin1; He, Hong-Yon1; Dolbecq, Anne2; Marrot, Jerome2; Keita, Bineta3; Zhi, Linjie4; Mialane, Pierre2; Li, Bin5; Zhang, Guangjin1
2017-11-08
Source PublicationACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
Volume9Issue:44Pages:38486-38498
Abstract

A series of carbonaceous-supported precious metal-free polyoxometalate (POM)-based composites which can be easily synthesized on a large scale was shown to act as efficient cathode materials for the oxygen reduction reaction (ORR) in neutral or basic media via a four-electron mechanism with high durability. Moreover, exploiting the versatility of the considered system, its activity was optimized by the judicious choice of the 3d metals incorporated in the {(PW9)(2)M-7} (M = Co, Ni) POM core, the POM counterions and the support (thermalized triazine-based frameworks (TTFs), fluorine doped TTF (TTF-F), reduced graphene oxide, or carbon Vulcan XC-72. In particular, for {(PW9)(2)Ni-7}/{Cu(ethylenediamine)(2)}/TTF-F, the overpotential required to drive the ORR compared well with those of Pt/C. This outstanding ORR electrocatalytic activity is linked with two synergistic effects due to the binary combination of the Cu and Ni centers and the strong interaction between the POM molecules and the porous and highly conducting TTF-F framework. To our knowledge, {(PW9)(2)Ni-7}/{Cu(ethylenediamine)(2)}/TTF-F represents the first example of POM-based noble-metal-free ORR electrocatalyst possessing both comparable ORR electrocatalytic activity and much higher stability than that of Pt/C in neutral medium.

KeywordCarbonaceous Materials Oxygen Reduction Reaction Polyoxometalate Neutral Medium Basic Medium
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1021/acsami.7b10989
Indexed BySCI
Language英语
WOS KeywordWATER OXIDATION ; RECENT PROGRESS ; AIR BATTERIES ; CATALYSTS ; ELECTROCATALYSTS ; GRAPHENE ; FUEL ; FACILE ; POLYOXOTUNGSTATES ; NANOMATERIALS
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
Funding OrganizationNational Natural Science Foundation of China(91545125 ; Youth Innovation Promotion Association of CAS ; CNRS ; Ministere de l'Enseignement Superieur et de la Recherche ; Universite Paris-Saclay ; Universite de Versailles Saint-Quentin ; U1662121)
WOS IDWOS:000415140800036
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23445
Collection湿法冶金清洁生产技术国家工程实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Versailles St Quentin Yvelines, Univ Paris Saclay, Inst Lavoisier Versailles, UMR 8180, 45 Ave Etats Unis, F-78035 Versailles, France
3.Univ Paris 11, Lab Chim Phys, CNRS, UMR 8000, F-91405 Orsay, France
4.Natl Ctr Nanosci & Technol, Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
5.Zhengzhou Tobacco Res Inst CNTC, Zhengzhou 450001, Henan, Peoples R China
6.Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes,Minist Educ,Inst Mol &, Jinan 250014, Shandong, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Shuangshuang,Oms, Olivier,Hao, Long,et al. High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(44):38486-38498.
APA Zhang, Shuangshuang.,Oms, Olivier.,Hao, Long.,Liu, Rongji.,Wang, Meng.,...&Zhang, Guangjin.(2017).High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports.ACS APPLIED MATERIALS & INTERFACES,9(44),38486-38498.
MLA Zhang, Shuangshuang,et al."High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports".ACS APPLIED MATERIALS & INTERFACES 9.44(2017):38486-38498.
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