High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports
Zhang, Shuangshuang1,6; Oms, Olivier2; Hao, Long4; Liu, Rongji1; Wang, Meng1; Zhang, Yaqin1; He, Hong-Yon1; Dolbecq, Anne2; Marrot, Jerome2; Keita, Bineta3; Zhi, Linjie4; Mialane, Pierre2; Li, Bin5; Zhang, Guangjin1
2017-11-08
发表期刊ACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
卷号9期号:44页码:38486-38498
摘要

A series of carbonaceous-supported precious metal-free polyoxometalate (POM)-based composites which can be easily synthesized on a large scale was shown to act as efficient cathode materials for the oxygen reduction reaction (ORR) in neutral or basic media via a four-electron mechanism with high durability. Moreover, exploiting the versatility of the considered system, its activity was optimized by the judicious choice of the 3d metals incorporated in the {(PW9)(2)M-7} (M = Co, Ni) POM core, the POM counterions and the support (thermalized triazine-based frameworks (TTFs), fluorine doped TTF (TTF-F), reduced graphene oxide, or carbon Vulcan XC-72. In particular, for {(PW9)(2)Ni-7}/{Cu(ethylenediamine)(2)}/TTF-F, the overpotential required to drive the ORR compared well with those of Pt/C. This outstanding ORR electrocatalytic activity is linked with two synergistic effects due to the binary combination of the Cu and Ni centers and the strong interaction between the POM molecules and the porous and highly conducting TTF-F framework. To our knowledge, {(PW9)(2)Ni-7}/{Cu(ethylenediamine)(2)}/TTF-F represents the first example of POM-based noble-metal-free ORR electrocatalyst possessing both comparable ORR electrocatalytic activity and much higher stability than that of Pt/C in neutral medium.

关键词Carbonaceous Materials Oxygen Reduction Reaction Polyoxometalate Neutral Medium Basic Medium
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1021/acsami.7b10989
收录类别SCI
语种英语
关键词[WOS]WATER OXIDATION ; RECENT PROGRESS ; AIR BATTERIES ; CATALYSTS ; ELECTROCATALYSTS ; GRAPHENE ; FUEL ; FACILE ; POLYOXOTUNGSTATES ; NANOMATERIALS
WOS研究方向Science & Technology - Other Topics ; Materials Science
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
项目资助者National Natural Science Foundation of China(91545125 ; Youth Innovation Promotion Association of CAS ; CNRS ; Ministere de l'Enseignement Superieur et de la Recherche ; Universite Paris-Saclay ; Universite de Versailles Saint-Quentin ; U1662121)
WOS记录号WOS:000415140800036
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23445
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Versailles St Quentin Yvelines, Univ Paris Saclay, Inst Lavoisier Versailles, UMR 8180, 45 Ave Etats Unis, F-78035 Versailles, France
3.Univ Paris 11, Lab Chim Phys, CNRS, UMR 8000, F-91405 Orsay, France
4.Natl Ctr Nanosci & Technol, Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
5.Zhengzhou Tobacco Res Inst CNTC, Zhengzhou 450001, Henan, Peoples R China
6.Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes,Minist Educ,Inst Mol &, Jinan 250014, Shandong, Peoples R China
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Zhang, Shuangshuang,Oms, Olivier,Hao, Long,et al. High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(44):38486-38498.
APA Zhang, Shuangshuang.,Oms, Olivier.,Hao, Long.,Liu, Rongji.,Wang, Meng.,...&Zhang, Guangjin.(2017).High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports.ACS APPLIED MATERIALS & INTERFACES,9(44),38486-38498.
MLA Zhang, Shuangshuang,et al."High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports".ACS APPLIED MATERIALS & INTERFACES 9.44(2017):38486-38498.
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