CAS OpenIR  > 研究所(批量导入)
Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction
Zhou, Jingxin1; Liu, Yamei1; Jiao, Tifeng1,2; Xing, Ruirui1,3; Yang, Zhiqiang1; Fan, Jizhou4; Liu, Jianzhao4; Li, Bingbing4; Peng, Qiuming2
2018-02-05
发表期刊COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN0927-7757
卷号538期号:00页码:7-13
摘要

Facile preparation and UV stabilization of electrospun poly(e-caprolactone) (PCL)/2-methyl-3-(trimethoxysilyl) propylester (M8POSS)/pentaerythritol tetrakis(3-mercaptopropionate) (PETM) composite fibers via thiol-ene click reaction were investigated. The morphological studies clearly showed the M8POSS and PETM macromers were excluded from PCL crystalline phase during electrospinning. The cross-linking reaction occurs in the amorphous phase of PCL fibers and possibly the fiber surface. By locking amorphous PCL chains into the crosslinked M8POSS and PETM through thiol-ene click reaction, we are able to fabricate PCL/POSS composite fibers, which can remain structural stability under UVC for longer period of time. The facile fabrication of the composite fibers via thiol-ene click reaction reported here provided valuable insight into not only the surface coating of medical devices but also new biocompatible composite materials.

关键词Poly(Epsilon-caprolactone) Electrospraying Thiol-ene Click Reaction Nanostructure
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.colsurfa.2017.10.077
收录类别SCI
语种英语
关键词[WOS]Waste-water Treatment ; Fabrication ; Photopolymerization ; Nanofibers
WOS研究方向Chemistry
WOS类目Chemistry, Physical
项目资助者National Natural Science Foundation of China(21473153) ; Support Program for the Top Young Talents of Hebei Province ; China Postdoctoral Science Foundation(2015M580214) ; Scientific and Technological Research and Development Program of Qinhuangdao City(201701B004) ; Undergraduate Training Programs for Innovation and Entrepreneurship of Hebei Province(201710216099)
WOS记录号WOS:000418586600002
引用统计
被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23450
专题研究所(批量导入)
通讯作者Jiao, Tifeng; Li, Bingbing
作者单位1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
4.Cent Michigan Univ, Dept Chem, Sci Adv Mat Doctoral Program, Mt Pleasant, MI 48859 USA
推荐引用方式
GB/T 7714
Zhou, Jingxin,Liu, Yamei,Jiao, Tifeng,et al. Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2018,538(00):7-13.
APA Zhou, Jingxin.,Liu, Yamei.,Jiao, Tifeng.,Xing, Ruirui.,Yang, Zhiqiang.,...&Peng, Qiuming.(2018).Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,538(00),7-13.
MLA Zhou, Jingxin,et al."Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 538.00(2018):7-13.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhou, Jingxin]的文章
[Liu, Yamei]的文章
[Jiao, Tifeng]的文章
百度学术
百度学术中相似的文章
[Zhou, Jingxin]的文章
[Liu, Yamei]的文章
[Jiao, Tifeng]的文章
必应学术
必应学术中相似的文章
[Zhou, Jingxin]的文章
[Liu, Yamei]的文章
[Jiao, Tifeng]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。