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Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction
Zhou, Jingxin1; Liu, Yamei1; Jiao, Tifeng1,2; Xing, Ruirui1,3; Yang, Zhiqiang1; Fan, Jizhou4; Liu, Jianzhao4; Li, Bingbing4; Peng, Qiuming2
2018-02-05
Source PublicationCOLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN0927-7757
Volume538Issue:00Pages:7-13
Abstract

Facile preparation and UV stabilization of electrospun poly(e-caprolactone) (PCL)/2-methyl-3-(trimethoxysilyl) propylester (M8POSS)/pentaerythritol tetrakis(3-mercaptopropionate) (PETM) composite fibers via thiol-ene click reaction were investigated. The morphological studies clearly showed the M8POSS and PETM macromers were excluded from PCL crystalline phase during electrospinning. The cross-linking reaction occurs in the amorphous phase of PCL fibers and possibly the fiber surface. By locking amorphous PCL chains into the crosslinked M8POSS and PETM through thiol-ene click reaction, we are able to fabricate PCL/POSS composite fibers, which can remain structural stability under UVC for longer period of time. The facile fabrication of the composite fibers via thiol-ene click reaction reported here provided valuable insight into not only the surface coating of medical devices but also new biocompatible composite materials.

KeywordPoly(Epsilon-caprolactone) Electrospraying Thiol-ene Click Reaction Nanostructure
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.colsurfa.2017.10.077
Indexed BySCI
Language英语
WOS KeywordWaste-water Treatment ; Fabrication ; Photopolymerization ; Nanofibers
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationNational Natural Science Foundation of China(21473153) ; Support Program for the Top Young Talents of Hebei Province ; China Postdoctoral Science Foundation(2015M580214) ; Scientific and Technological Research and Development Program of Qinhuangdao City(201701B004) ; Undergraduate Training Programs for Innovation and Entrepreneurship of Hebei Province(201710216099)
WOS IDWOS:000418586600002
Citation statistics
Cited Times:39[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23450
Collection研究所(批量导入)
Corresponding AuthorJiao, Tifeng; Li, Bingbing
Affiliation1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
4.Cent Michigan Univ, Dept Chem, Sci Adv Mat Doctoral Program, Mt Pleasant, MI 48859 USA
Recommended Citation
GB/T 7714
Zhou, Jingxin,Liu, Yamei,Jiao, Tifeng,et al. Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2018,538(00):7-13.
APA Zhou, Jingxin.,Liu, Yamei.,Jiao, Tifeng.,Xing, Ruirui.,Yang, Zhiqiang.,...&Peng, Qiuming.(2018).Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,538(00),7-13.
MLA Zhou, Jingxin,et al."Preparation and enhanced structural integrity of electrospun poly(epsilon-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 538.00(2018):7-13.
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