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Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route
Liu, Hong-hui1,2,3; Zhang, Hong-ling2,3; Xu, Hong-bin2,3; Lou, Tai-ping1; Sui, Zhi-tong1; Zhang, Yi1,2,3
2018-02-01
Source PublicationCERAMICS INTERNATIONAL
ISSN0272-8842
Volume44Issue:2Pages:1583-1588
Abstract

In this research, hierarchically nanostructured vanadium nitride (VN) microspheres were successfully prepared by a template-free method. ZnO, behaving as a sacrificial phase, was selectively leached out during nitridation of Zn-3(OH)(2)(V2O7)center dot(H2O)(2) microspheres with NH3, inducing a network structure. The VN microsphere was assembled with porous nanosheets. Extraordinary, the VN microsphere mimicked the morphology of the initial precursor and exhibited a rose-like morphology. The diameter of the microsphere was in the range of 1-3 mu m, and the thickness of the porous.nanosheets was typically approximately 30 nm. In addition, this facile and novel synthetic strategy can be further extended to the preparation of other hierarchically nanostructured transition metal nitrides.

KeywordTemplate-free Method Vanadium Nitride Zno Nitridation
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1016/j.ceramint.2017.10.078
Indexed BySCI
Language英语
WOS KeywordOxygen Reduction Reaction ; Transition-metal Nitrides ; Nanocrystalline Vn ; Supercapacitors ; Deposition ; Separation ; Coatings ; Behavior ; Storage ; Oxides
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Ceramics
Funding OrganizationNational Basic Research Program of China (973 Program)(2013CB632606)
WOS IDWOS:000418211600046
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23456
Collection研究所(批量导入)
Corresponding AuthorZhang, Hong-ling
Affiliation1.Northeastern Univ, Sch Met, Shenyang 110819, Liaoning, Peoples R China
2.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Liu, Hong-hui,Zhang, Hong-ling,Xu, Hong-bin,et al. Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route[J]. CERAMICS INTERNATIONAL,2018,44(2):1583-1588.
APA Liu, Hong-hui,Zhang, Hong-ling,Xu, Hong-bin,Lou, Tai-ping,Sui, Zhi-tong,&Zhang, Yi.(2018).Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route.CERAMICS INTERNATIONAL,44(2),1583-1588.
MLA Liu, Hong-hui,et al."Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route".CERAMICS INTERNATIONAL 44.2(2018):1583-1588.
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