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Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route
Liu, Hong-hui1,2,3; Zhang, Hong-ling2,3; Xu, Hong-bin2,3; Lou, Tai-ping1; Sui, Zhi-tong1; Zhang, Yi1,2,3
2018-02-01
发表期刊CERAMICS INTERNATIONAL
ISSN0272-8842
卷号44期号:2页码:1583-1588
摘要

In this research, hierarchically nanostructured vanadium nitride (VN) microspheres were successfully prepared by a template-free method. ZnO, behaving as a sacrificial phase, was selectively leached out during nitridation of Zn-3(OH)(2)(V2O7)center dot(H2O)(2) microspheres with NH3, inducing a network structure. The VN microsphere was assembled with porous nanosheets. Extraordinary, the VN microsphere mimicked the morphology of the initial precursor and exhibited a rose-like morphology. The diameter of the microsphere was in the range of 1-3 mu m, and the thickness of the porous.nanosheets was typically approximately 30 nm. In addition, this facile and novel synthetic strategy can be further extended to the preparation of other hierarchically nanostructured transition metal nitrides.

关键词Template-free Method Vanadium Nitride Zno Nitridation
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1016/j.ceramint.2017.10.078
收录类别SCI
语种英语
关键词[WOS]Oxygen Reduction Reaction ; Transition-metal Nitrides ; Nanocrystalline Vn ; Supercapacitors ; Deposition ; Separation ; Coatings ; Behavior ; Storage ; Oxides
WOS研究方向Materials Science
WOS类目Materials Science, Ceramics
项目资助者National Basic Research Program of China (973 Program)(2013CB632606)
WOS记录号WOS:000418211600046
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23456
专题研究所(批量导入)
通讯作者Zhang, Hong-ling
作者单位1.Northeastern Univ, Sch Met, Shenyang 110819, Liaoning, Peoples R China
2.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Liu, Hong-hui,Zhang, Hong-ling,Xu, Hong-bin,et al. Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route[J]. CERAMICS INTERNATIONAL,2018,44(2):1583-1588.
APA Liu, Hong-hui,Zhang, Hong-ling,Xu, Hong-bin,Lou, Tai-ping,Sui, Zhi-tong,&Zhang, Yi.(2018).Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route.CERAMICS INTERNATIONAL,44(2),1583-1588.
MLA Liu, Hong-hui,et al."Hierarchically nanostructured vanadium nitride microspheres assembled with porous nanosheets fabricated by a template-free route".CERAMICS INTERNATIONAL 44.2(2018):1583-1588.
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