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In Situ Self-Assembly-Generated 3D Hierarchical Co3O4 Micro/Nanomaterial Series: Selective Synthesis, Morphological Control, and Energy Applications | |
Miao, Qingqing; Zhang, Suojiang | |
2017-12-20 | |
Source Publication | ACS APPLIED MATERIALS & INTERFACES
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ISSN | 1944-8244 |
Volume | 9Issue:50Pages:44199-44213 |
Abstract | A simple in situ self-assembly selective synthetic strategy for onestep controllable formation of various three-dimensional (3D) hierarchical Co3O4 micro/nanomaterials with peculiar morphologies, uniform size, and high quality is successfully developed. The Morphological control and related impact factors are investigated and clarified in detail. The results further clarify the corresponding mechanisms on the reaction process, product generation, and calcining process as well as the formation of specific morphologies. Furthermore, the superior catalytic properties of these materials are confirmed by two typical Co-based energy applications on the decomposition of an important solid rocket propellant, ammonium perchlorate (AP), and dye-sensitized solar cells (DSSCs). The addition of Co3O4 materials to AP obviously decreases the decomposition temperatures by about 118-140 degrees C and increases the exothermic heat to a great extent. As the substituted counter electrodes of DSSCs, the 3D hierarchical Co3O4 materials exhibit attractive photovoltaic performances. These findings provide a facile and: effective way for designing new types of 3D hierarchical materials toward high catalytic activity for energy devices. |
Keyword | In Situ 3d Hierarchical Co3o4 Micro/nanomaterials Superior Catalytic Properties Ammonium Perchlorate Dye-sensitized Solar Cells |
Subtype | Article |
WOS Headings | Science & Technology ; Technology |
DOI | 10.1021/acsami.7b14543 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | Sensitized Solar-cells ; Lithium-ion Batteries ; Chemical-vapor-deposition ; Electrochemical Performance ; Nanowire Arrays ; Water Oxidation ; Storage Properties ; Mesoporous Co3o4 ; High-efficiency ; Hollow Spheres |
WOS Research Area | Science & Technology - Other Topics ; Materials Science |
WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
Funding Organization | National Natural Science Foundation of China(51203161 ; Key Laboratory of Green Process and Engineering, Chinese Academy of Sciences ; 21576264 ; 21436010 ; 91434203) |
WOS ID | WOS:000418783700090 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/23480 |
Collection | 研究所(批量导入) |
Corresponding Author | Zhang, Suojiang |
Affiliation | Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn,Inst Proc Engn, 1 Zhongguancun North Second St, Beijing 100190, Peoples R China |
Recommended Citation GB/T 7714 | Miao, Qingqing,Zhang, Suojiang. In Situ Self-Assembly-Generated 3D Hierarchical Co3O4 Micro/Nanomaterial Series: Selective Synthesis, Morphological Control, and Energy Applications[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(50):44199-44213. |
APA | Miao, Qingqing,&Zhang, Suojiang.(2017).In Situ Self-Assembly-Generated 3D Hierarchical Co3O4 Micro/Nanomaterial Series: Selective Synthesis, Morphological Control, and Energy Applications.ACS APPLIED MATERIALS & INTERFACES,9(50),44199-44213. |
MLA | Miao, Qingqing,et al."In Situ Self-Assembly-Generated 3D Hierarchical Co3O4 Micro/Nanomaterial Series: Selective Synthesis, Morphological Control, and Energy Applications".ACS APPLIED MATERIALS & INTERFACES 9.50(2017):44199-44213. |
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In Situ Self-Assembl(4851KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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