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Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling
Sun, Yong1; Jia, Zhe1; Yang, Gang2,3; Zhang, Lian4; Sun, Zhi5
2017-12-07
发表期刊INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
卷号42期号:49页码:29222-29235
摘要

Fischer-Tropsch (FT) synthesis was carried out in a microchannel reactor using an iron based catalyst. The performance of microchannel reactor was evaluated in the aspect of CO conversion versus time on stream, catalyst deactivation, pressure drop and gas hour space velocity. The result indicates an excellent mass and heat transfer in the micro channel reactor. The negative impact of external and internal film diffusional limitation could be avoided in this microchannel reactor at experimental conditions. The effect of reaction temperature, operational pressure, syngas ratio and space velocity upon CO conversion and hydrocarbon selectivity were extensively investigated. The kinetic modeling was conducted and the mechanisms i.e. carbide, enlic, alkyl, formate and CO insertion were extensively explored, A mechanism derived from Eley-Rideal-type mechanism was found to be the most statistical and physical relevance at the experimental conditions during FT synthesis using iron-based catalyst in this microchannel reactor. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

关键词Fischer-tropsch Synthesis Iron-based Catalyst Microchannel Reactor Kinetic Modeling
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.ijhydene.2017.10.022
收录类别SCI
语种英语
关键词[WOS]Microstructured Reactors ; Heterogeneous Catalysis ; Slurry Phase ; Conversion ; Mechanism ; Gas ; Temperature ; Liquids ; Olefin ; Fuels
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels
WOS类目Chemistry, Physical ; Electrochemistry ; Energy & Fuels
项目资助者Anpeng high-tech energy-resources Co. Ltd
WOS记录号WOS:000418317100017
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23487
专题研究所(批量导入)
通讯作者Sun, Yong
作者单位1.Edith Cowan Univ, Sch Engn, 270 Joondalup Dr, Joondalup, WA 6027, Australia
2.Anpeng High Tech Energy Corp, Beijing, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Acid Base Coupled Prod Technol, Beijing 100190, Peoples R China
4.Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
5.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Sun, Yong,Jia, Zhe,Yang, Gang,et al. Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(49):29222-29235.
APA Sun, Yong,Jia, Zhe,Yang, Gang,Zhang, Lian,&Sun, Zhi.(2017).Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(49),29222-29235.
MLA Sun, Yong,et al."Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.49(2017):29222-29235.
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