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Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling | |
Sun, Yong1; Jia, Zhe1; Yang, Gang2,3; Zhang, Lian4; Sun, Zhi5 | |
2017-12-07 | |
Source Publication | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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ISSN | 0360-3199 |
Volume | 42Issue:49Pages:29222-29235 |
Abstract | Fischer-Tropsch (FT) synthesis was carried out in a microchannel reactor using an iron based catalyst. The performance of microchannel reactor was evaluated in the aspect of CO conversion versus time on stream, catalyst deactivation, pressure drop and gas hour space velocity. The result indicates an excellent mass and heat transfer in the micro channel reactor. The negative impact of external and internal film diffusional limitation could be avoided in this microchannel reactor at experimental conditions. The effect of reaction temperature, operational pressure, syngas ratio and space velocity upon CO conversion and hydrocarbon selectivity were extensively investigated. The kinetic modeling was conducted and the mechanisms i.e. carbide, enlic, alkyl, formate and CO insertion were extensively explored, A mechanism derived from Eley-Rideal-type mechanism was found to be the most statistical and physical relevance at the experimental conditions during FT synthesis using iron-based catalyst in this microchannel reactor. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
Keyword | Fischer-tropsch Synthesis Iron-based Catalyst Microchannel Reactor Kinetic Modeling |
Subtype | Article |
WOS Headings | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.ijhydene.2017.10.022 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | Microstructured Reactors ; Heterogeneous Catalysis ; Slurry Phase ; Conversion ; Mechanism ; Gas ; Temperature ; Liquids ; Olefin ; Fuels |
WOS Research Area | Chemistry ; Electrochemistry ; Energy & Fuels |
WOS Subject | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
Funding Organization | Anpeng high-tech energy-resources Co. Ltd |
WOS ID | WOS:000418317100017 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/23487 |
Collection | 研究所(批量导入) |
Corresponding Author | Sun, Yong |
Affiliation | 1.Edith Cowan Univ, Sch Engn, 270 Joondalup Dr, Joondalup, WA 6027, Australia 2.Anpeng High Tech Energy Corp, Beijing, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Acid Base Coupled Prod Technol, Beijing 100190, Peoples R China 4.Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia 5.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China |
Recommended Citation GB/T 7714 | Sun, Yong,Jia, Zhe,Yang, Gang,et al. Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(49):29222-29235. |
APA | Sun, Yong,Jia, Zhe,Yang, Gang,Zhang, Lian,&Sun, Zhi.(2017).Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(49),29222-29235. |
MLA | Sun, Yong,et al."Fischer-Tropsch synthesis using iron based catalyst in a microchannel reactor: Performance evaluation and kinetic modeling".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.49(2017):29222-29235. |
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Fischer-Tropsch synt(2057KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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