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Ionic Liquid Droplet Microreactor for Catalysis Reactions Not at Equilibrium
Zhang, Ming1; Ettelaie, Rammile2; Yan, Tao1; Zhang, Suojiang3; Cheng, Fangqin4; Binks, Bernard P.5; Yang, Hengquan1
2017-12-06
发表期刊JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
卷号139期号:48页码:17387-17396
摘要

We develop a novel strategy to more effectively and controllably process continuous enzymatic or homogeneous catalysis reactions based on nonaqueous Pickering emulsions. A key element of this strategy is "bottom-up" construction of a macroscale continuous flow reaction system through packing catalyst-containing micron-sized ionic liquid (IL) droplet in oil in a column reactor. Due to the continuous influx of reactants into the droplet microreactors and the continuous release of products from the droplet microreactors, catalysis reactions in such a system can take place without limitations arising from establishment of the reaction equilibrium and catalyst separation, inherent in conventional batch reactions. As proof of the concept, enzymatic enantioselective transesterification and CuI-catalyzed cycloaddition reactions using this IL droplet-based flow system both exhibit 8 to 25-fold enhancement in catalysis efficiency compared to their batch counterparts, and a durability of at least 4000 h for the enantioselective trans-esterification of 1-phenylethyl alcohol, otherwise unattainable in their batch counterparts. We further establish a theoretical model for such a catalysis system working under nonequilibrium conditions, which not only supports the experimental results but also helps to predict reaction progress at a microscale level. Being operationally simple, efficient, and adaptive, this strategy provides an unprecedented platform for practical applications of enzymes and homogeneous catalysts even at a controllable level.

文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1021/jacs.7b07731
收录类别SCI
语种英语
关键词[WOS]Biocatalytic Reductive Amination ; Continuous-flow ; Pickering Emulsions ; Heterogeneous Catalysts ; Homogeneous Catalysis ; Silica Nanoparticles ; Chemical-synthesis ; Biphasic Systems ; Separation ; Hydroformylation
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
项目资助者Natural Science Foundation of China(21733009 ; Program for New Century Excellent Talents in University(NECT-12-1030) ; Program for Youth Sanjin Scholar ; 21573136 ; U1510105)
WOS记录号WOS:000417669000035
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23489
专题研究所(批量导入)
通讯作者Yang, Hengquan
作者单位1.Shanxi Univ, Sch Chem & Chem Engn, Inst Mol Sci, Taiyuan 030006, Shanxi, Peoples R China
2.Univ Leeds, Food Colloids Grp, Sch Food Sci & Nutr, Leeds LS2 9JT, W Yorkshire, England
3.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
4.Shanxi Univ, Inst Resources & Environm Engn, Taiyuan 030006, Shanxi, Peoples R China
5.Univ Hull, Sch Math & Phys Sci, Kingston Upon Hull HU6 7RX, N Humberside, England
推荐引用方式
GB/T 7714
Zhang, Ming,Ettelaie, Rammile,Yan, Tao,et al. Ionic Liquid Droplet Microreactor for Catalysis Reactions Not at Equilibrium[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(48):17387-17396.
APA Zhang, Ming.,Ettelaie, Rammile.,Yan, Tao.,Zhang, Suojiang.,Cheng, Fangqin.,...&Yang, Hengquan.(2017).Ionic Liquid Droplet Microreactor for Catalysis Reactions Not at Equilibrium.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(48),17387-17396.
MLA Zhang, Ming,et al."Ionic Liquid Droplet Microreactor for Catalysis Reactions Not at Equilibrium".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.48(2017):17387-17396.
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