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| Solubility of NaHCO3 and NH4HCO3 in the Relevant Media and Prediction of High-Pressure Phase Equilibria for the NH3-CO2-NaCl-H2O System | |
| Zhou, Juan1; Zeng, Yan2; Demopoulos, George P.2; Li, Chunxi1; Li, Zhibao3 | |
| 2017-12-01 | |
| Source Publication | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| ISSN | 0021-9568 |
| Volume | 62Issue:12Pages:4401-4410 |
| Abstract | The solubility of NaHCO3 was determined in the NH4+-Na+-CO32--HCO3--Cl--H2O system with the concentration up to 6 mol.kg(-1) by a dynamic method from 283.15 to 333.15 K. It was found that the solubility of NaHCO3 decreases with increasing concentration of Na2CO3, NH4HCO3, or NaCl. A speciation-based model was developed with mixed-solvent electrolyte interaction parameters newly obtained by regressing both the experimental and literature solubility data. The average relative deviations are less than 5.0%. The new model is able to predict the solubility of NaHCO3 at high pressures up to 6.0 MPa for the NH3-CO2-NaCl-H2O system at 313.15 and 323.15 K. This work can provide a theoretical basis for producing Na2CO3 with a better crystal form and higher productivity in the carbonation process. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1021/acs.jced.7b00790 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | Solvent Electrolyte Systems ; Na2sio3-center-dot-9h(2)o ; Speciation ; Water |
| WOS Research Area | Thermodynamics ; Chemistry ; Engineering |
| WOS Subject | Thermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical |
| Funding Organization | National Natural Science Foundation of China(21476235 ; 21776279 ; U1407112) |
| WOS ID | WOS:000418393800039 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/23496 |
| Collection | 研究所（批量导入） |
| Corresponding Author | Li, Zhibao |
| Affiliation | 1.Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China 2.McGill Univ, Mat Engn, 3610 Univ St, Montreal, PQ H3A 0C5, Canada 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Zhou, Juan,Zeng, Yan,Demopoulos, George P.,et al. Solubility of NaHCO3 and NH4HCO3 in the Relevant Media and Prediction of High-Pressure Phase Equilibria for the NH3-CO2-NaCl-H2O System[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2017,62(12):4401-4410. |
| APA | Zhou, Juan,Zeng, Yan,Demopoulos, George P.,Li, Chunxi,&Li, Zhibao.(2017).Solubility of NaHCO3 and NH4HCO3 in the Relevant Media and Prediction of High-Pressure Phase Equilibria for the NH3-CO2-NaCl-H2O System.JOURNAL OF CHEMICAL AND ENGINEERING DATA,62(12),4401-4410. |
| MLA | Zhou, Juan,et al."Solubility of NaHCO3 and NH4HCO3 in the Relevant Media and Prediction of High-Pressure Phase Equilibria for the NH3-CO2-NaCl-H2O System".JOURNAL OF CHEMICAL AND ENGINEERING DATA 62.12(2017):4401-4410. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Solubility of NaHCO3（1709KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text | |
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