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Synthesis of Cu/ZnO Flower-like Hierarchical Porous Structures and Investigation of Their Catalytic Performance for Dimethyl Oxalate Hydrogenation
San Xiaoguang; Zhao Guodong; Wang Guosheng; Qi Jian; Jin Quan; Meng Dan
2017
发表期刊CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY
ISSN1008-6234
卷号19期号:00页码:40
摘要

The Cu/ZnO flower-like hierarchical porous structures were successfully synthesized via the cetyltrimethyl ammonium bromide (CTAB) assisted hydrothermal method. The morphology and structure as well as the catalytic performance for dimethyl oxalate (DMO) hydrogenation to ethylene glycol (EG) were investigated. Through annealing the zinc copper hydroxide carbonate (ZCHC) precursors, the Cu/ZnO flower-like hierarchical porous structures were obtained, which were assembled by a number of porous nanosheets. The catalyst made of these well-defined flower-like hierarchical porous structures with large specific surface area and effective gas diffusion path via the well-aligned porous structures showed higher EG selectivity and yield as compared to the Cu/ZnO catalyst obtained by conventional co-precipitation technique. The results indicated that the Cu/ZnO flower-like hierarchical porous structures have excellent potential application for manufacture of high performance catalysts.

关键词Hierarchical Porous Structure Cu/zno Catalyst Dimethyl Oxalate Hydrogenation
文章类型Article
语种英语
WOS记录号WOS:000406849500006
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23521
专题研究所(批量导入)
通讯作者Meng Dan
推荐引用方式
GB/T 7714
San Xiaoguang,Zhao Guodong,Wang Guosheng,et al. Synthesis of Cu/ZnO Flower-like Hierarchical Porous Structures and Investigation of Their Catalytic Performance for Dimethyl Oxalate Hydrogenation[J]. CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY,2017,19(00):40.
APA San Xiaoguang,Zhao Guodong,Wang Guosheng,Qi Jian,Jin Quan,&Meng Dan.(2017).Synthesis of Cu/ZnO Flower-like Hierarchical Porous Structures and Investigation of Their Catalytic Performance for Dimethyl Oxalate Hydrogenation.CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY,19(00),40.
MLA San Xiaoguang,et al."Synthesis of Cu/ZnO Flower-like Hierarchical Porous Structures and Investigation of Their Catalytic Performance for Dimethyl Oxalate Hydrogenation".CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY 19.00(2017):40.
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