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Highly controlled synthesis of multi-shelled NiO hollow microspheres for enhanced lithium storage properties
Li, Hao; Ma, Haoran; Yang, Mei; Wang, Sao; Shao, Hui; Wang, Lei; Yu, Ranbo; Wang, Dan
2017
Source PublicationMATERIALS RESEARCH BULLETIN
ISSN0025-5408
Volume87Issue:00Pages:224
Abstract

Nickel oxide microspheres with porous multi-shelled structure were synthesized via a sequential templating approach using carbonaceous microspheres (CMSs) as sacrificial agent. When applied as anode material for lithium ion batteries, the as-prepared porous triple-shelled NiO hollow spheres show excellent cycling performance and outstanding high-rate capability, as well as high specific capacity. During all the 100 discharge-charge cycles under a current density of 500 mA/g, the porous triple-shelled NiO hollow spheres can stably deliver a reversible capacity of ca. 789 mAh/g. Even at a high current density of 2000 mA/g, the specific discharge capacity of the porous triple-shelled Ni0 hollow spheres is still as high as 721 mAh/g, which is twice larger than that of commercial graphite. The superior electrochemical performance can be attributed to the porous multi-shelled hollow microstructure which guarantees more lithium-storage sites, a shorter lithium-ion diffusion length, and sufficient void space to buffer the volume expansion. (C) 2016 Elsevier Ltd. All rights reserved.

KeywordAnode Performance Anode Materials High-rate Capability Electrochemical Energy-storage Lithium-ion Battery Large-scale Synthesis Multi-shelled Structure Ion Batteries Nio Accurate Control Intercalation Nanospheres Challenges Capacity
SubtypeArticle
DOI10.1016/j.materresbull.2016.12.005
WOS IDWOS:000392681800033
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23529
Collection研究所(批量导入)
Corresponding AuthorYang, Mei; Wang, Lei; Yu, Ranbo; Wang, Dan
Recommended Citation
GB/T 7714
Li, Hao,Ma, Haoran,Yang, Mei,et al. Highly controlled synthesis of multi-shelled NiO hollow microspheres for enhanced lithium storage properties[J]. MATERIALS RESEARCH BULLETIN,2017,87(00):224.
APA Li, Hao.,Ma, Haoran.,Yang, Mei.,Wang, Sao.,Shao, Hui.,...&Wang, Dan.(2017).Highly controlled synthesis of multi-shelled NiO hollow microspheres for enhanced lithium storage properties.MATERIALS RESEARCH BULLETIN,87(00),224.
MLA Li, Hao,et al."Highly controlled synthesis of multi-shelled NiO hollow microspheres for enhanced lithium storage properties".MATERIALS RESEARCH BULLETIN 87.00(2017):224.
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