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Morphology-dependent catalytic properties of nanocupric oxides in the Rochow reaction
Zhang, Yu1,2; Ji, Yongjun1; Li, Jing1,2; Liu, Hezhi1; Hu, Xiao3; Zhong, Ziyi3; Su, Fabing1
2018-02-01
发表期刊NANO RESEARCH
ISSN1998-0124
卷号11期号:2页码:804-819
摘要Four kinds of CuO catalysts with well-controlled leaf-like (L-CuO), flower-like (F-CuO), sea-urchin-like (U-CuO), and oatmeal-like (O-CuO) morphologies were synthesized by a facile precipitation method assisted by various chelating ligands. High-resolution transmission electron microscopy and fast Fourier transform infrared spectroscopy indicated that the dominant crystal facets of L-CuO, F-CuO, U-CuO, and O-CuO were {001}, {(1) over bar 10}, {001}, and {110}, as well as {001} and {(1) over bar 10}, respectively. When tested for the Rochow reaction, it was found that their catalytic performances were dependent on their structures. Among the four CuO catalysts, L-CuO exhibited the best catalytic property, along with the strongest adsorption ability for oxygen and highest reducibility, which are mainly because of its largely exposed {001} facet and large specific surface area. In addition, the amount of the Cu3Si alloy phase, which is the most important reaction intermediate that generated in the reacted region of the Si surface, was measured for the different catalysts. Based on the findings, a detailed reaction mechanism was proposed. This work demonstrates that shape-controlled synthesis of oxide catalysts could be an effective strategy to design and develop efficient catalysts.
关键词Copper Oxide Shape-controlled Synthesis The Rochow Reaction The Cu3si Alloy Phase Structure-property Relationship
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1007/s12274-017-1689-x
收录类别SCI
语种英语
关键词[WOS]CONTROLLABLE SYNTHESIS ; CUO NANOSTRUCTURES ; CO OXIDATION ; METHYLCHLOROSILANES ; NANOCRYSTALS ; MECHANISM ; PERFORMANCE ; KINETICS ; FACILE ; OXYGEN
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
项目资助者National Natural Science Foundation of China(21506224)
WOS记录号WOS:000419959500020
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23587
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Nanyang Technol Univ, NEWRI, 1 Cleantech Loop,CleanTech One, Singapore 637141, Singapore
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Zhang, Yu,Ji, Yongjun,Li, Jing,et al. Morphology-dependent catalytic properties of nanocupric oxides in the Rochow reaction[J]. NANO RESEARCH,2018,11(2):804-819.
APA Zhang, Yu.,Ji, Yongjun.,Li, Jing.,Liu, Hezhi.,Hu, Xiao.,...&Su, Fabing.(2018).Morphology-dependent catalytic properties of nanocupric oxides in the Rochow reaction.NANO RESEARCH,11(2),804-819.
MLA Zhang, Yu,et al."Morphology-dependent catalytic properties of nanocupric oxides in the Rochow reaction".NANO RESEARCH 11.2(2018):804-819.
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