One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids

doi:10.1021/acs.iecr.7b04947

	One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids
	Yan, Dongxia 1,2,3; Wang, Gongying 1; Gao, Kai 2,3; Lu, Xingmei 2,3; Xin, Jiayu 2; Zhang, Suojiang 2
	2018-02-14
发表期刊	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN	0888-5885
卷号	57 期号:6 页码:1851-1858
摘要	2,5-Furandicarboxylic acid (FDCA), which is usually produced from HMF catalyzed by noble metal catalysts, is an important biobased monomer for the degradable polymer polyethylene furandicarboxylate (PEF). In order to reduce the high costs of starting material and catalysts, a novel approach for the direct conversion of fructose into FDCA was developed by employing [Bmim]Cl as a solvent with non-noble metal (Fe-Zr-O) as a catalyst. Relatively high FDCA yield was obtained at full fructose conversion under optimal conditions. The kinetic study revealed that the oxidation of intermediate FFCA to FDCA possessed the highest activation energy, indicating this step is most affected by reaction temperature: Additionally, in the IL-promoted reaction system, other biomass sources, such as glucose, galactose, mannose, starch, and cellulose also can be directly converted, with lower FDCA yield compared with that of fructose due to the ineffective isomerization of aldohexoses into fructose.
文章类型	Article
WOS标题词	Science & Technology ; Technology
DOI	10.1021/acs.iecr.7b04947
收录类别	SCI
语种	英语
关键词[WOS]	SELECTIVE AEROBIC OXIDATION ; CATALYTIC CONVERSION ; RENEWABLE RESOURCES ; MILD CONDITIONS ; LEVULINIC ACID ; BIOMASS ; CHEMICALS ; GLUCOSE ; 2,5-DIFORMYLFURAN ; CHLORIDE
WOS研究方向	Engineering
WOS类目	Engineering, Chemical
项目资助者	National Key Technology R&D Program of China(2016YFB0301900) ; National Natural Science Foundation of China(21576269 ; Science & Technology Pillar Program of Sichuan Province(2015GZ0065) ; 21210006 ; 21506231)
WOS记录号	WOS:000425473900009
引用统计
文献类型	期刊论文
条目标识符	http://ir.ipe.ac.cn/handle/122111/23996
专题	多相复杂系统国家重点实验室
作者单位	1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc,Key Lab, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yan, Dongxia,Wang, Gongying,Gao, Kai,et al. One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(6):1851-1858.
APA	Yan, Dongxia,Wang, Gongying,Gao, Kai,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2018).One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(6),1851-1858.
MLA	Yan, Dongxia,et al."One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.6(2018):1851-1858.