| One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids | |
| Yan, Dongxia1,2,3; Wang, Gongying1; Gao, Kai2,3; Lu, Xingmei2,3; Xin, Jiayu2; Zhang, Suojiang2 | |
| 2018-02-14 | |
| Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| ISSN | 0888-5885 |
| Volume | 57Issue:6Pages:1851-1858 |
| Abstract | 2,5-Furandicarboxylic acid (FDCA), which is usually produced from HMF catalyzed by noble metal catalysts, is an important biobased monomer for the degradable polymer polyethylene furandicarboxylate (PEF). In order to reduce the high costs of starting material and catalysts, a novel approach for the direct conversion of fructose into FDCA was developed by employing [Bmim]Cl as a solvent with non-noble metal (Fe-Zr-O) as a catalyst. Relatively high FDCA yield was obtained at full fructose conversion under optimal conditions. The kinetic study revealed that the oxidation of intermediate FFCA to FDCA possessed the highest activation energy, indicating this step is most affected by reaction temperature: Additionally, in the IL-promoted reaction system, other biomass sources, such as glucose, galactose, mannose, starch, and cellulose also can be directly converted, with lower FDCA yield compared with that of fructose due to the ineffective isomerization of aldohexoses into fructose. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Technology |
| DOI | 10.1021/acs.iecr.7b04947 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | SELECTIVE AEROBIC OXIDATION ; CATALYTIC CONVERSION ; RENEWABLE RESOURCES ; MILD CONDITIONS ; LEVULINIC ACID ; BIOMASS ; CHEMICALS ; GLUCOSE ; 2,5-DIFORMYLFURAN ; CHLORIDE |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Chemical |
| Funding Organization | National Key Technology R&D Program of China(2016YFB0301900) ; National Natural Science Foundation of China(21576269 ; Science & Technology Pillar Program of Sichuan Province(2015GZ0065) ; 21210006 ; 21506231) |
| WOS ID | WOS:000425473900009 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/23996 |
| Collection | 多相复杂系统国家重点实验室 |
| Affiliation | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc,Key Lab, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Yan, Dongxia,Wang, Gongying,Gao, Kai,et al. One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(6):1851-1858. |
| APA | Yan, Dongxia,Wang, Gongying,Gao, Kai,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2018).One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(6),1851-1858. |
| MLA | Yan, Dongxia,et al."One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.6(2018):1851-1858. |
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