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One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids
Yan, Dongxia1,2,3; Wang, Gongying1; Gao, Kai2,3; Lu, Xingmei2,3; Xin, Jiayu2; Zhang, Suojiang2
2018-02-14
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume57Issue:6Pages:1851-1858
Abstract2,5-Furandicarboxylic acid (FDCA), which is usually produced from HMF catalyzed by noble metal catalysts, is an important biobased monomer for the degradable polymer polyethylene furandicarboxylate (PEF). In order to reduce the high costs of starting material and catalysts, a novel approach for the direct conversion of fructose into FDCA was developed by employing [Bmim]Cl as a solvent with non-noble metal (Fe-Zr-O) as a catalyst. Relatively high FDCA yield was obtained at full fructose conversion under optimal conditions. The kinetic study revealed that the oxidation of intermediate FFCA to FDCA possessed the highest activation energy, indicating this step is most affected by reaction temperature: Additionally, in the IL-promoted reaction system, other biomass sources, such as glucose, galactose, mannose, starch, and cellulose also can be directly converted, with lower FDCA yield compared with that of fructose due to the ineffective isomerization of aldohexoses into fructose.
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1021/acs.iecr.7b04947
Indexed BySCI
Language英语
WOS KeywordSELECTIVE AEROBIC OXIDATION ; CATALYTIC CONVERSION ; RENEWABLE RESOURCES ; MILD CONDITIONS ; LEVULINIC ACID ; BIOMASS ; CHEMICALS ; GLUCOSE ; 2,5-DIFORMYLFURAN ; CHLORIDE
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Key Technology R&D Program of China(2016YFB0301900) ; National Natural Science Foundation of China(21576269 ; Science & Technology Pillar Program of Sichuan Province(2015GZ0065) ; 21210006 ; 21506231)
WOS IDWOS:000425473900009
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/23996
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc,Key Lab, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yan, Dongxia,Wang, Gongying,Gao, Kai,et al. One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(6):1851-1858.
APA Yan, Dongxia,Wang, Gongying,Gao, Kai,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2018).One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(6),1851-1858.
MLA Yan, Dongxia,et al."One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.6(2018):1851-1858.
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