CAS OpenIR  > 多相复杂系统国家重点实验室
One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids
Yan, Dongxia1,2,3; Wang, Gongying1; Gao, Kai2,3; Lu, Xingmei2,3; Xin, Jiayu2; Zhang, Suojiang2
2018-02-14
发表期刊INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
卷号57期号:6页码:1851-1858
摘要2,5-Furandicarboxylic acid (FDCA), which is usually produced from HMF catalyzed by noble metal catalysts, is an important biobased monomer for the degradable polymer polyethylene furandicarboxylate (PEF). In order to reduce the high costs of starting material and catalysts, a novel approach for the direct conversion of fructose into FDCA was developed by employing [Bmim]Cl as a solvent with non-noble metal (Fe-Zr-O) as a catalyst. Relatively high FDCA yield was obtained at full fructose conversion under optimal conditions. The kinetic study revealed that the oxidation of intermediate FFCA to FDCA possessed the highest activation energy, indicating this step is most affected by reaction temperature: Additionally, in the IL-promoted reaction system, other biomass sources, such as glucose, galactose, mannose, starch, and cellulose also can be directly converted, with lower FDCA yield compared with that of fructose due to the ineffective isomerization of aldohexoses into fructose.
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1021/acs.iecr.7b04947
收录类别SCI
语种英语
关键词[WOS]SELECTIVE AEROBIC OXIDATION ; CATALYTIC CONVERSION ; RENEWABLE RESOURCES ; MILD CONDITIONS ; LEVULINIC ACID ; BIOMASS ; CHEMICALS ; GLUCOSE ; 2,5-DIFORMYLFURAN ; CHLORIDE
WOS研究方向Engineering
WOS类目Engineering, Chemical
项目资助者National Key Technology R&D Program of China(2016YFB0301900) ; National Natural Science Foundation of China(21576269 ; Science & Technology Pillar Program of Sichuan Province(2015GZ0065) ; 21210006 ; 21506231)
WOS记录号WOS:000425473900009
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/23996
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc,Key Lab, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Yan, Dongxia,Wang, Gongying,Gao, Kai,et al. One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(6):1851-1858.
APA Yan, Dongxia,Wang, Gongying,Gao, Kai,Lu, Xingmei,Xin, Jiayu,&Zhang, Suojiang.(2018).One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(6),1851-1858.
MLA Yan, Dongxia,et al."One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.6(2018):1851-1858.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Yan, Dongxia]的文章
[Wang, Gongying]的文章
[Gao, Kai]的文章
百度学术
百度学术中相似的文章
[Yan, Dongxia]的文章
[Wang, Gongying]的文章
[Gao, Kai]的文章
必应学术
必应学术中相似的文章
[Yan, Dongxia]的文章
[Wang, Gongying]的文章
[Gao, Kai]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。