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An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid
He, Nan1,2; Gong, Yafeng2,3; Yang, Yidi4; Wang, Yi2; Qin, Chuanguang1; Wang, Rumin1; Liu, Jiehua3; Qi, Tao2
2018-02-08
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
Volume43Issue:6Pages:3216-3222
Abstract

The Pd@Ni-B/C catalysts were prepared by using Ni-B/C with different amounts of Ni-B alloys as supports. The structure, morphology and element valence state of these catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS), respectively. The electro-catalytic performance of these catalysts for formic acid oxidation was investigated using cyclic voltammetry (CV), chronoamperometry (CA) and CO stripping experiments. It was found that an appropriate amount of Ni-B alloys plays an important role in enhancing catalytic activity and resistance to CO poisoning and improving stability of Pd based catalysts, all of which imply that PdONi1.61B0.0199/C is promising for probable applications in direct formic acid fuel cell field. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

KeywordNi-b Alloys Pd Electrocatalysts Formic Acid Oxidation Fuel Cells
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.ijhydene.2017.12.167
Indexed BySCI
Language英语
WOS KeywordCarbon Nanotubes Catalyst ; Reduced Graphene Oxide ; Fuel-cells ; Oxidation Reaction ; Hydrogen Storage ; Nanoparticles ; Performance ; Support ; Electrocatalysts ; Deactivation
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
Funding OrganizationOne Hundred Talent Program of Chinese Academy of Sciences ; 973 Program(2015CB251303)
WOS IDWOS:000426225000013
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/24011
Collection湿法冶金清洁生产技术国家工程实验室
Affiliation1.Northwestern Polytech Univ, Sch Nat & Appl Sci, Xian 710072, Shaanxi, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
3.Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
4.Tongji Univ, Coll Environm Sci & Engn, Shanghai 200092, Peoples R China
Recommended Citation
GB/T 7714
He, Nan,Gong, Yafeng,Yang, Yidi,et al. An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2018,43(6):3216-3222.
APA He, Nan.,Gong, Yafeng.,Yang, Yidi.,Wang, Yi.,Qin, Chuanguang.,...&Qi, Tao.(2018).An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,43(6),3216-3222.
MLA He, Nan,et al."An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 43.6(2018):3216-3222.
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