B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity
Zhang, Zejun1,2; Zhang, Yanqiang1,3; Li, Zhimin1; Jiao, Nianming1,2; Liu, Long1,4; Zhang, Suojiang1
2018-02-28
发表期刊EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
期号8页码:981-986
摘要In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H122- were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8-286.3 degrees C; densities: 1.215-1.264 gcm(-3)). The results demonstrate their promising applications in bipropellant formulations.
关键词Propellants Hypergolic Fuels Transition Metals Ionic Liquids Boron
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/ejic.201701206
收录类别SCI
语种英语
关键词[WOS]ENERGETIC IONIC LIQUIDS ; IGNITION-DELAY TIMES ; ROCKET FUELS ; HYDRAZINE DERIVATIVES ; REPLACEMENTS ; OXIDIZERS ; CHEMISTRY ; FLUIDS
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
项目资助者National Natural Science Foundation of China(21576270 ; National Key Research and Development Program of China(2016YFB0600903) ; 21676281)
WOS记录号WOS:000426501400003
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/24022
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Div Ion Liquids & Green Engn, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Henan, Peoples R China
4.Lab Particle Sci & Engn, Beijing 100049, Peoples R China
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Zhang, Zejun,Zhang, Yanqiang,Li, Zhimin,et al. B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2018(8):981-986.
APA Zhang, Zejun,Zhang, Yanqiang,Li, Zhimin,Jiao, Nianming,Liu, Long,&Zhang, Suojiang.(2018).B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(8),981-986.
MLA Zhang, Zejun,et al."B12H122--Based Metal (Cu2+, Ni2+, Zn2+) Complexes as Hypergolic Fuels with Superior Hypergolicity".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .8(2018):981-986.
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