Simple and efficient polyoxomolybdate-mediated synthesis of novel graphene and metal nanohybrids for versatile applications
Zhang, Shuangshuang1,6; Liu, Rongji1,7; Li, Shiwen1; Dolbecq, Anne2; Mialane, Pierre2; Suo, Lin3; Bi, Lihua3; Zhang, Baofang4; Liu, Tianbo4; Wu, Caixia5; Yan, Likai5; Su, Zhongmin5; Zhang, Guangjin1; Keita, Bineta8
2018-03-15
发表期刊JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN0021-9797
卷号514页码:507-516
摘要The application of nanohybrids based on polyoxomolybdates, reduced graphene oxide (rGO) and/or metal nanoparticles (NPs) high-performance electrode materials in electrocatalysis and energy storage devices is promising but still limited due to the complexity and the cost of the synthesis. Here we introduce a simple polyoxomolybdate, [(Mo4O8)-O-V(OH)(2)(H2O)(2)(C4O4)(2)](2-) (MoS), as reducing and stabilizing agent for the facile and one-pot syntheses of large quantity of highly stable MoS/rGO and MoS/Au NPs nanohybrids in aqueous solution without any catalyst or toxic co-solvent. They were characterized by various physical techniques and electrochemistry which confirm strong interaction between MoS and rGO sheets. We also used DFT calculations to investigate the affinity between MoS or its neutral form with graphene. The adsorption energy for the most stable configuration is -1.97 eV, indicating a strong adsorption process of MoS, which can also be confirmed by the distance (3.04 angstrom) and the charge transfer (0.86 e) between MoS and graphene. These observations are also consistent with the electrochemical results which underscore the excellent redox properties and high stability of MoS/rGO. Importantly, the MoS/rGO nanohybrids are excellent noble metal-free electrocatalysts for hydrogen peroxide reduction with high sensitivity, large detection range and low detection limit. Finally, the preliminary tests reveal that the electrode materials based on MoS/rGO and a low-cost carbon cloth (CC) composite MoS/rGO/CC may have a potential for an application in energy storage as performant and flexible supercapacitor, showing specific capacitance as high as 870 F g(-1) at 10 mV s(-1) and excellent stability after 5000 cycles. (C) 2017 Elsevier Inc. All rights reserved.
关键词Multifunction Materials Reduced Graphene Oxide Polyoxomolybdate Sensor For Hydrogen Peroxide Flexible Supercapacitor Electrodes
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.jcis.2017.12.039
收录类别SCI
语种英语
关键词[WOS]LARGE-SCALE SYNTHESIS ; ORGANIC FRAMEWORKS ; NANOPOROUS CARBONS ; GREEN SYNTHESIS ; LARGE SYSTEMS ; POLYOXOMETALATE ; OXIDE ; SUPERCAPACITORS ; CATALYSIS ; WATER
WOS研究方向Chemistry
WOS类目Chemistry, Physical
项目资助者National Natural Science Foundation of China(91545125 ; Youth Innovation Promotion Association of CAS ; CNRS ; Ministere de l'Enseignement Superieur et de la Recherche ; Universite Paris-Saclay ; Universite de Versailles Saint-Quentin ; NSF(CHE1607138) ; University of Akron ; U1662121 ; 21173102 ; 21473072)
WOS记录号WOS:000424963700055
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/24053
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Paris Saclay, Inst Lavoisier Versailles, UVSQ, CNRS, Versailles, France
3.Jilin Univ, Coll Chem, Changchun 130012, Jilin, Peoples R China
4.Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
5.Northeast Normal Univ, Fac Chem, Changchun 130024, Jilin, Peoples R China
6.Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Coll Chem Chem Engn & Mat Sci, Key Lab Mol & Nano Probes,Minist Educ,Inst Mol &, Jinan 250014, Shandong, Peoples R China
7.Ulm Univ, Inst Inorgan Chem 1, Albert Einstein Allee 11, D-89081 Ulm, Germany
8.Univ Paris 11, UMR CNRS 8000, Lab Chim Phys, F-91405 Orsay, France
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Zhang, Shuangshuang,Liu, Rongji,Li, Shiwen,et al. Simple and efficient polyoxomolybdate-mediated synthesis of novel graphene and metal nanohybrids for versatile applications[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2018,514:507-516.
APA Zhang, Shuangshuang.,Liu, Rongji.,Li, Shiwen.,Dolbecq, Anne.,Mialane, Pierre.,...&Keita, Bineta.(2018).Simple and efficient polyoxomolybdate-mediated synthesis of novel graphene and metal nanohybrids for versatile applications.JOURNAL OF COLLOID AND INTERFACE SCIENCE,514,507-516.
MLA Zhang, Shuangshuang,et al."Simple and efficient polyoxomolybdate-mediated synthesis of novel graphene and metal nanohybrids for versatile applications".JOURNAL OF COLLOID AND INTERFACE SCIENCE 514(2018):507-516.
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