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Amino functionalized [B12H12](2-) salts as hypergolic fuels
Li, Hao1,2; Zhang, Yanqiang1; Liu, Long1; Jiao, Nianming1,3; Meng, Xianghai2; Zhang, Suojiang1
2018-03-07
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume42Issue:5Pages:3568-3573
Abstract

A series of hypergolic salts based on [B12H11NH3](-) anion were synthesized. The resulting six salts were characterized by H-1 and C-13 NMR, IR, ESI-MS and EA. Their key properties were measured or calculated, including melting points (133.9-210.7 degrees C), decomposition temperatures (215.6-278.2 degrees C), and heats of formation (-40.1 to 1073.0 J g(-1)). As expected, the [B12H11NH3](-) salts (1-6) possess higher specific impulses (274.9-276.8 s) than the corresponding [B12H12](2-) salts (269.8-272.6 s). When the fuel/oxidizer combinations range from 20% to 50%, specific impulse values of the salts are still maintained at a high level of above 269 s.

SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c7nj04225f
Indexed BySCI
Language英语
WOS KeywordEnergetic Ionic Liquids ; Anions ; Nanoparticles ; Chemistry ; Ignition ; Fluids
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationNational Natural Science Foundation of China(21676281 ; International Cooperation and Exchange of the National Natural Science Foundation of China(51561145020) ; 21576270)
WOS IDWOS:000426488900047
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/24070
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Div Ion Liquids & Green Engn, Beijing 100190, Peoples R China
2.China Univ Petr, Sch Chem Engn, Beijing 102249, Peoples R China
3.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Hao,Zhang, Yanqiang,Liu, Long,et al. Amino functionalized [B12H12](2-) salts as hypergolic fuels[J]. NEW JOURNAL OF CHEMISTRY,2018,42(5):3568-3573.
APA Li, Hao,Zhang, Yanqiang,Liu, Long,Jiao, Nianming,Meng, Xianghai,&Zhang, Suojiang.(2018).Amino functionalized [B12H12](2-) salts as hypergolic fuels.NEW JOURNAL OF CHEMISTRY,42(5),3568-3573.
MLA Li, Hao,et al."Amino functionalized [B12H12](2-) salts as hypergolic fuels".NEW JOURNAL OF CHEMISTRY 42.5(2018):3568-3573.
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