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Fabrication and application of hierarchical mesoporous MoO2/Mo2C/C microspheres
Li, Xiaoyan1,2,3; Xiao, Qinggui1,2; Zhang, Hongling1,2; Xu, Hongbin1,2; Zhang, Yi1,2

Hierarchical mesoporous MoO2/Mo2C/C microspheres, which are composed of primary nanoparticles with a size of about 30 nm, have been designed and synthesized through polymer regulation and subsequent carbonization processes. The as-synthesized microspheres were characterized by XRD, Raman, SEM, TEM, XPS measurements and so on. It was found that polyethylene glycol acted as a structure-directing agent, mild reducing agent and carbon source in the formation of these hierarchical mesoporous MoO2/Mo2C/C microspheres. Moreover, the electrochemical property of the microspheres was also investigated in this work. Evaluated as an anode material for lithium ion batteries, the hierarchical mesoporous MoO2/Mo2C/C electrode delivered the discharge specific capacities of 665 and 588 mAh/g after 100 cycles at current densities of 100 and 200 mA/g, respectively. The satisfactory cycling performance and controllable process facilitate the practical applications of the hierarchical mesoporous MoO2/Mo2C/C as a potential anode material in high-energy density lithium-ion batteries. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

KeywordLithium Ion Batteries Anode Materials Moo2/mo2c/c Mesoporous Polymer Regulation
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
Indexed BySCI
WOS KeywordLithium-ion Batteries ; Carbon Nanotubes ; Anode Materials ; Hollow Microspheres ; Electrochemical Performance ; Electrode Materials ; Cathode Materials ; Moo2 ; Storage ; Capacity
WOS Research AreaChemistry ; Energy & Fuels ; Engineering
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
Funding OrganizationNational Natural Science Foundation of China(21376251 ; National Basic Research Development Program of China(2013CB632600) ; 21406233)
WOS IDWOS:000430515900037
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Document Type期刊论文
Affiliation1.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Xiaoyan,Xiao, Qinggui,Zhang, Hongling,et al. Fabrication and application of hierarchical mesoporous MoO2/Mo2C/C microspheres[J]. JOURNAL OF ENERGY CHEMISTRY,2018,27(3):940-948.
APA Li, Xiaoyan,Xiao, Qinggui,Zhang, Hongling,Xu, Hongbin,&Zhang, Yi.(2018).Fabrication and application of hierarchical mesoporous MoO2/Mo2C/C microspheres.JOURNAL OF ENERGY CHEMISTRY,27(3),940-948.
MLA Li, Xiaoyan,et al."Fabrication and application of hierarchical mesoporous MoO2/Mo2C/C microspheres".JOURNAL OF ENERGY CHEMISTRY 27.3(2018):940-948.
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