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A metal-free direct C (sp(3))-H cyanation reaction with cyanobenziodoxolones
Sun, Ming-Xue1,2; Wang, Yao-Feng2; Xu, Bao-Hua2; Ma, Xin-Qi1; Zhang, Suo-Jiang2
2018-03-21
发表期刊ORGANIC & BIOMOLECULAR CHEMISTRY
ISSN1477-0520
卷号16期号:11页码:1971-1975
摘要A metal-free protocol of direct C(sp(3))-H cyanation with cyanobenziodoxolones functioning as both cyanating reagents and oxidants was developed. Unactivated substrates, such as alkanes, ethers and tertiary amines, were thereby transformed to the corresponding nitriles in moderate to high yields. Mechanistic studies indicated that the cyanation proceeded with two potential pathways, which is highly dependent on the substrates: (1) a free radical case for alkanes and ethers and (2) an oxidative case for tertiary amines.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c8ob00173a
收录类别SCI
语种英语
关键词[WOS]BETA-KETO-ESTERS ; ELECTROPHILIC CYANATION ; ALPHA-CYANATION ; TERTIARY-AMINES ; STRECKER REACTION ; ATOM-TRANSFER ; EBX REAGENTS ; H BONDS ; ALKYNYLATION ; OXINDOLES
WOS研究方向Chemistry
WOS类目Chemistry, Organic
项目资助者National Science Foundation of China(21606238 ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; CAS 100-Talent Program ; 21476240 ; U1662133)
WOS记录号WOS:000428222500020
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/24141
专题多相复杂系统国家重点实验室
作者单位1.Henan Univ, Henan Engn Res Ctr Resource & Energy Recovery Was, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China
2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
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Sun, Ming-Xue,Wang, Yao-Feng,Xu, Bao-Hua,et al. A metal-free direct C (sp(3))-H cyanation reaction with cyanobenziodoxolones[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2018,16(11):1971-1975.
APA Sun, Ming-Xue,Wang, Yao-Feng,Xu, Bao-Hua,Ma, Xin-Qi,&Zhang, Suo-Jiang.(2018).A metal-free direct C (sp(3))-H cyanation reaction with cyanobenziodoxolones.ORGANIC & BIOMOLECULAR CHEMISTRY,16(11),1971-1975.
MLA Sun, Ming-Xue,et al."A metal-free direct C (sp(3))-H cyanation reaction with cyanobenziodoxolones".ORGANIC & BIOMOLECULAR CHEMISTRY 16.11(2018):1971-1975.
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