| MnO2-nanowire@NiO-nanosheet core-shell hybrid nanostructure derived interfacial Effect for promoting catalytic oxidation activity | |
Deng, Yuzhou1,2; Tang, Wenxiang3,4; Li, Wenhui1; Chen, Yunfa1
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| 2018-06-15 | |
| Source Publication | CATALYSIS TODAY
 |
| ISSN | 0920-5861 |
| Volume | 308Pages:58-63 |
| Abstract | Nanostructure-derived interfacial effect plays a great role in enhancing catalytic activities. Herein, a MnO2 nanowires@NiO nanosheets core-shell hybrid nanostructure was successfully prepared by uniformly decorating NiO nanosheets on the one-dimensional MnO2 nanowires. The physi-chemical properties of the MnO2 and MnO2@NiO were characterized by using XRD, BET, SEM, H-2-TPR and XPS techniques. Compared to the single MnO2 nanowires, the MnO2@NiO nanocomposite with better low-temperature reducibility and more active surface oxygen species exhibited much better performance in complete oxidation of benzene, giving the temperatures for 100% benzene conversion of 320 degrees C under the conditions of 1000 ppm benzene in air and space velocity of 120,000 mL g(-1) h(-1) while the value over pure MnO2 was 380 degrees C. The novel hetero-interface constructed between MnO2 and NiO core-shell nanostructures might make a great contribution on this significantly promoting effect. |
| Keyword | Interfacial Effect Mno2-nanowires@nio-nanosheets Hybrid Nanostructure Catalytic Oxidation Benzene |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1016/j.cattod.2017.07.007 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | COMPLETE BENZENE OXIDATION ; TRANSITION-METAL OXIDES ; LOW-TEMPERATURE ; DEEP OXIDATION ; TOLUENE COMBUSTION ; COMPOSITE OXIDES ; GASEOUS BENZENE ; DOPED CEO2 ; MN ; PERFORMANCE |
| WOS Research Area | Chemistry ; Engineering |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| Funding Organization | Chinese Academy of Sciences(XDB05050000) |
| WOS ID | WOS:000429527800008 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/24145 |
| Collection | 多相复杂系统国家重点实验室 |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Connecticut, Dept Mat Sci & Engn, 97 N Eagleville Rd, Storrs, CT 06269 USA 4.Univ Connecticut, Inst Mat Sci, 97 N Eagleville Rd, Storrs, CT 06269 USA |
| Recommended Citation GB/T 7714 | Deng, Yuzhou,Tang, Wenxiang,Li, Wenhui,et al. MnO2-nanowire@NiO-nanosheet core-shell hybrid nanostructure derived interfacial Effect for promoting catalytic oxidation activity[J]. CATALYSIS TODAY,2018,308:58-63. |
| APA | Deng, Yuzhou,Tang, Wenxiang,Li, Wenhui,&Chen, Yunfa.(2018).MnO2-nanowire@NiO-nanosheet core-shell hybrid nanostructure derived interfacial Effect for promoting catalytic oxidation activity.CATALYSIS TODAY,308,58-63. |
| MLA | Deng, Yuzhou,et al."MnO2-nanowire@NiO-nanosheet core-shell hybrid nanostructure derived interfacial Effect for promoting catalytic oxidation activity".CATALYSIS TODAY 308(2018):58-63. |
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